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MATERIAL
SAFETY DATA SHEET
IMR
POWDER COMPANY
IDENTIFICATION
NAME: SINGLE BASE SMOKELESS POWDER
Trade Names and Synonyms:
IMR ####, SR ####, PB
####= Number Designation for Products
MANUFACTURER
Product Information Phone: (913) 362-9455
HAZARDOUS COMPONENTS
CHEMICAL
CAS NUMBER
Nitrocellulose
9004-70-0
2, 4-Dinitrotoluene
121-14-2
PHYSICAL DATA
Specific Gravity:
1.65
Solubility in
H20: Negligible
Color:
Black
Form:
Perforated or non perforated small discs or
perforated cylinders.
HAZARDOUS REACTIVITY
INSTABILITY:
Unstable with heat, Unstable with static charges. Unstable with
impact. Not hazardous if product used properly.
INCOMPATIBILITY:
Incompatible with acids, alkalis, oxidants.
DECOMPOSITION:
Decomposes with heat. Hazardous gases produced are carbon monoxide.
Decomposes with impact, static charges.
POLYMERIZATION:
Polymerization will not occur.
FIRE AND EXPLOSION DATA
Ignition temperature: 160-170 degC
FIRE AND EXPLOSION HAZARDS
Hazardous gases produced in fire are carbon monoxide. 1.3C
Explosive (DOT)>100 lbs.;
Flammable Solid 100 lbs. or less. Burns uncontrollably. Produces
shrapnel if confined.
EXTINGUISHING MEDIA
None
SPECIAL FIRE FIGHTING INSTRUCTIONS
Do not fight fire. Isolate area. Evacuate personnel to a safe area.
Guard against intruders.
HEALTH HAZARD
INFORMATION
PRINCIPAL HEALTH HAZARDS
These products have not been tested for toxicity. They are 1.3C Explosives
and burning, confined or unconfined, can cause physical injury, including
death. The toxicity effects given below for the hazardous components may
result from gross chronic or acute overexposure to the products by
inhalation, eye or skin contact or ingestion.
2, 4-DINITROTOLUENE
Inhalation LC50: 2.87 mg/1, 1 hour in rats.
Skin absorption ALD: >1,000 mg/kg in rabbits.
Oral LD50: 177 mg/kg in rats.
This compound is toxic by inhalation and ingestion.
It is a skin and eye irritant. Toxic effects described in animals from
exposure by inhalation, ingestion, or skin contact include nonspecific
effects such as reduced weight gain, methemoglobinemia
and effects on the central nervous system, the reproductive system, and bone
marrow. In animal tests, technical grade 2,4-dinitrotoluene
has carcinogenic activity. Tests for mutagenic activity in bacterial and
mammalian cell cultures have been both positive and negative. It has
demonstrated no embryo toxic activity in animals. It produces testicular
degeneration and decreased spermatogenesis in rats, mice and dogs. Reduction
in male fertility occurs in dominant lethal studies in rats.
Human health effects from overexposure by inhalation, skin or eye
contact, or ingestion may initially include reduction of the blood's oxygen
carrying capacity with cyanosis, weakness, or shortness of breath by methemoglobin formation; nonspecific discomfort such as
nausea, headache, confusion, incoordination, loss
of consciousness; temporary lung irritation effects with cough, discomfort,
difficulty breathing, or shortness of breath; or joint pain. The compound
appears to be able to significantly permeate the skin. Individuals with
pre-existing diseases of the central nervous system, peripheral nervous
system, lungs, or reproductive organs may have increased susceptibility to
the toxicity of excessive exposures.
NITROCELLULOSE
Oral LD50: >5,000 mg/kg in rats
The compound is not a skin or eye irritant.
CARCINOGENICITY
None of the component(s) of this material is listed as a carcinogen by
HTP, IARC, or OSHA
EXPOSURE LIMITS
TLV* (ACGIH) : None established.
PEL (OSHA) : None established.
*TLV is a registered trademark.
2,4-Dinotrotoluene: AEL 0.5mg/M3, 8&12 hr TWA Skin
PEL (OSHA) 1.5mg/M3, skin
TLV (ACGIH) 1.5mg/M3, skin
SAFETY INFORMATION
SAFETY PRECAUTIONS
Do not breathe dust. Do not get in eyes. Do not get on skin. Do not
get on clothing. Wash thoroughly after handling. Wash clothing after use.
Don't breathe burning powder fumes. Keep out of reach of children.
FIRST AID
INHALATION:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen.
Call a physician.
SKIN CONTACT:
In case of contact, wash skin with soap and plenty of water.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Call a physician.
INGESTION
If swallowed, induce vomiting immediately by giving two glasses of
water and sticking finger down throat. Never give anything by mouth to an
unconscious person. Call a physician.
NOTE: Burning smokeless powder may cause extensive and deep burns.
Get medical attention immediately. Immerse burned area in cold water.
NOTE TO PHYSICIAN: Absorption of 2,4-Dinitrotoluene into the body
may lead to the formation of methemoglobin that, in
sufficient concentration, causes cyanosis, since reversion of methemoglobin to hemoglobin occurs spontaneously after
termination of exposure, moderate degrees of cyanosis need be treated only by
supportive measures such as bed rest and oxygen inhalation. Thorough
cleansing of the entire contaminated area of the body, including scalp and
nails is the utmost importance. If cyanosis is severe, intravenous injection
of methylene blue, one milligram per kilogram of
body weight, may be of value. Cyanocobalamin
(Vitamin B12), one milligram intramuscularly, may speed recovery. Intravenous
fluids and blood transfusions may be indicated in very severe exposure.
PROTECTION
INFORMATION
GENERALLY APPLICABLE CONTROL MEASURES AND PRECAUTIONS
Use only with adequate ventilation. Keep away from heat, sparks and flames.
Keep container in a cool place. Keep container tightly closed. Avoid dust
generation. Do not mix with acids or alkalis. Do not consume food, drink or
tobacco in areas where they may become contaminated with this material. Use
spark proof tools and equipment. Do not allow powder to accumulate in exhaust
systems.
PERSONAL PROTECTIVE EQUIPMENT
Safety glasses. Protective cotton gloves.
SPILL, LEAK, OR
RELEASE
Review FIRE AND EXPLOSION HAZARDS AND SAFETY PRECAUTIONS before
proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during
clean up.
Control access to area. Remove source of heat, sparks, flame, impact,
friction or electricity. Pick up by hand for disposal. Do no use power
equipment. Do not use damaged or wet material. Never return to container for
reuse. Use non sparking tools for cleanup.
WASTE DISPOSAL
Do not burn. Consult an explosives manufacturer for recommended
methods of destroying explosive materials. Comply with applicable Federal
Regulations under the authority of the Resource Conservation and Recovery Act
(40 CFR, parts 260-271). May be stored under water until disposed of.
SHIPPING INFORMATION
Check manufacturer or shipper for specific information.
STORAGE CONDITIONS
Store in well ventilated area. Store in cool place. Keep container tightly
closed. Do not store with other explosives. Store in accordance with National
Fire Protection Assoc. regulations. Store in accordance with Federal
Regulations. Do not store or consume food, drink, or tobacco in areas where
they may become contaminated with this material. Store in approved type
magazine.
ADDITIONAL
INFORMATION AND REFERENCES
PERSONS HANDLING EXPLOSIVES MUST BE TRAINED IN THE CORRECT PROCEDURES
FOR THEIR USE.
Date of latest Revision: May, 1, 2001
Person Responsible for MSDS: Safety Officer
Address: P.O. Box 2932
Shawnee Mission,
KS 66201
Telephone: (913) 362-9455
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