MSDS Name: Buffer Solution pH 3.00
Catalog Numbers: S79928-2, S799282, SB97 20, SB97 500, SB9720, SB97500
Synonyms: None.
Company Identification:
              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use extinguishing media appropriate to the surrounding fire. Substance is nonflammable.
Extinguishing Media: Use water fog, dry chemical, carbon dioxide, or regular foam.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb the liquid and scrub the area with detergent and water. Pick up wash liquid with additional absorbent and place into a suitable disposable container.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. No special precautions indicated.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Good general ventilation should be sufficient to control airborne levels.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Formaldehyde	C 0.3 ppm	0.016 ppm TWA; NIOSH Potential Occupational Carcinogen - see Appendix A Potential NIOSH carcinogen.	0.75 ppm TWA PEL; 2 ppm STEL; 0.5 ppm TWA action leve
Methyl alcohol	200 ppm TWA; 250 ppm STEL; skin - potential for cutaneous absorption	200 ppm TWA; 260 mg/m3 TWA 6000 ppm IDLH	200 ppm TWA; 260 mg/m3 TWA
Potassium hydrogen phthalate	none listed	none listed	none listed
Hydrogen chloride	C 5 ppm	50 ppm IDLH	C 5 ppm; C 7 mg/m3
Water	none listed	none listed	none listed

OSHA Vacated PELs: Formaldehyde: 3 ppm TWA (unless specified in 1910.1048); 10 ppm STEL (30 min) (unless specified in 1910.1048); C 5 ppm (unless specified in 1910.1048) Methyl alcohol: 200 ppm TWA; 260 mg/m3 TWA; 250 ppm STEL; 325 mg/m3 STEL Potassium hydrogen phthalate: No OSHA Vacated PELs are listed for this chemical. Hydrogen chloride: C 5 ppm; C 7 mg/m3 Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate protective gloves to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: clear, colorless
Odor: none reported
pH: 3.00
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point:32 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble in water
Specific Gravity/Density:0.7
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: None reported.
Incompatibilities with Other Materials: None reported. This solution contains hydrochloric acid, which may react with metal containers.
Hazardous Decomposition Products: None.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:
CAS# 50-00-0: LP8925000
CAS# 67-56-1: PC1400000
CAS# 877-24-7: CZ4326000
CAS# 7647-01-0: MW4025000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 50-00-0:
Draize test, rabbit, eye: 750 ug/24H Severe;
Draize test, rabbit, eye: 750 ug Severe;
Draize test, rabbit, eye: 10 mg Severe;
Draize test, rabbit, skin: 2 mg/24H Severe;
Draize test, rabbit, skin: 50 mg/24H Moderate;
Inhalation, mouse: LC50 = 454 gm/m3/4H;
Inhalation, rat: LC50 = 203 mg/m3;
Oral, mouse: LD50 = 42 mg/kg;
Oral, rat: LD50 = 100 mg/kg;
Skin, rabbit: LD50 = 270 uL/kg;
CAS# 67-56-1:
Draize test, rabbit, eye: 40 mg Moderate;
Draize test, rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, skin: 20 mg/24H Moderate;
Inhalation, rat: LC50 = 64000 ppm/4H;
Oral, mouse: LD50 = 7300 mg/kg;
Oral, rabbit: LD50 = 14200 mg/kg;
Oral, rat: LD50 = 5628 mg/kg;
Skin, rabbit: LD50 = 15800 mg/kg;
CAS# 877-24-7:
Dermal, guinea pig: LD50 = >1 gm/kg;
Oral, rat: LD50 = >3200 mg/kg;
CAS# 7647-01-0:
Inhalation, mouse: LC50 = 1108 ppm/1H;
Inhalation, rat: LC50 = 3124 ppm/1H;
Oral, rabbit: LD50 = 900 mg/kg;
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 50-00-0:
ACGIH: A2 - Suspected Human Carcinogen
California: carcinogen; initial date 1/1/88
NIOSH: occupational carcinogen
NTP: Suspect carcinogen
OSHA: Possible Select carcinogen
IARC: Group 2A carcinogen CAS# 67-56-1: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 877-24-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7647-01-0:
IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: ~~Methanol has been shown to prooduce fetoxicity in the embr yo or fetus in laboratory animals. Specific developmenta l abnormalities include:musculoskeletal, urogenital and cardiovascular systems,
Teratogenicity: Effects on the newborn by exposure to formaldehyde have been reported in rats by inhalation, such as behavioral effects, biochemical and metabolic effects, and reduced weight gain. Cytological changes were also noted. Specific developmental abnormalities were reported by the intraperitoneal route of exposure in mice.
Reproductive Effects: Paternal effects were reported in male rats by inhalation, oral ingestion and intraperitoneal injection of formaldehyde. Organs affected included the prostate, seminal vesicle, Cowpers gland, urethra, testes, sperm duct and epididymis. Spermatogenesis was also affected.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: CAS# 50-00-0: waste number U122. CAS# 67-56-1: waste number U154; (Ignitable waste).

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	No information available.				No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 50-00-0 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 877-24-7 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
CAS# 50-00-0: final RQ = 100 pounds (45.4 kg) CAS# 67-56-1: final RQ = 5000 pounds (2270 kg) CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ)
CAS# 50-00-0: TPQ = 500 pounds; RQ = 100 pounds (does not meet toxici ty criteria but because of high production volume and recognized toxic ity is considered a chemical of concern) CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxi city criteria but because of high production volume and recognized tox icity is considered a chemical of concern)
SARA Codes
CAS # 50-00-0: acute, chronic. CAS # 67-56-1: acute, flammable. CAS # 877-24-7: acute. CAS # 7647-01-0: acute.
Section 313
This material contains Formaldehyde (CAS# 50-00-0, 0 05%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. This chemical is not at a high enough concentration to be reportable under Section 313. This chemical is not at a high enough concentration to be reportable under Section 313.
Clean Air Act:
CAS# 50-00-0 is listed as a hazardous air pollutant (HAP). CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 50-00-0 is listed as a Hazardous Substance under the CWA. CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 50-00-0 is considered highly hazardous by OSHA. CAS# 7647-01-0 is considered highly hazardous by OSHA.
STATE
CAS# 50-00-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 877-24-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
The following statement(s) is(are) made in order to comply with the California Safe Drinking Water Act: WARNING: This product contains Formaldehyde, a chemical known to the state of California to cause cancer. California No Significant Risk Level: CAS# 50-00-0: no significant risk level = 40 ug/day European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:

Safety Phrases:

WGK (Water Danger/Protection)
CAS# 50-00-0: 2
CAS# 67-56-1: 1
CAS# 877-24-7: No information available.
CAS# 7647-01-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 50-00-0 is listed on Canada's DSL List. CAS# 50-00-0 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 877-24-7 is listed on Canada's DSL List. CAS# 877-24-7 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.




This product has a WHMIS classification of Not controlled..
CAS# 50-00-0 is listed on Canada's Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 877-24-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 50-00-0: OEL-ARAB Republic of Egypt:TWA 2 ppm (3 mg/m3) OEL-AU
STRALIA:TWA 1 ppm (1.5 mg/m3);STEL 2 ppm (3 mg/m3);CAR OEL-BELGIUM:TW
A 1 ppm (1.2 mg/m3);STEL 2 ppm (2.5 mg/m3);CAR OEL-CZECHOSLOVAKIA:TWA
0.5 mg/m3;STEL 1 mg/m3 OEL-DENMARK:STEL 0.3 ppm (0.4 mg/m3);Carcinog
en OEL-FINLAND:STEL 1 ppm (1.3 mg/m3);Skin OEL-FRANCE:STEL 2 ppm (3
mg/m3) OEL-GERMANY:TWA 0.5 ppm (0.6 mg/m3);Carcinogen OEL-HUNGARY:ST
EL 0.6 mg/m3;Carcinogen OEL-JAPAN:TWA 0.5 ppm (0.61 mg/m3);Carcinogen
OEL-THE NETHERLANDS:TWA 1 ppm (1.5 mg/m3);STEL 2 ppm (3 mg/m3) OEL-
THE PHILIPPINES:TWA 5 ppm (6 mg/m3) OEL-POLAND:TWA 2 mg/m3 OEL-RUSSI
A:TWA 0.5 ppm;STEL 0.5 mg/m3;Skin OEL-SWEDEN:TWA 0.5 ppm (0.6 mg/m3);
STEL 1 ppm (1. mg/m3) OEL-SWITZERLAND:TWA 0.5 ppm (0.6 mg/m3);STEL 1
pp (1.2 mg/m3) OEL-THAILAND:TWA 3 ppm;STEL 5 ppm OEL-TURKEY:TWA 5 pp
m (6 mg/m3) OEL-UNITED KINGDOM:TWA 2 ppm (2.5 mg/m3);STEL 2 ppm (2.5
mg/m3) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL
IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 67-56-1: OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Ski
n OEL-AUSTRALIA:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL-BELGIU
M:TWA 200 ppm (262 mg/m3);STEL 250 ppm;Skin OEL-CZECHOSLOVAKIA:TWA 10
0 mg/m3;STEL 500 mg/m3 OEL-DENMARK:TWA 200 ppm (260 mg/m3);Skin OEL-
FINLAND:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL-FRANCE:TWA 200
ppm (260 mg/m3);STEL 1000 ppm (1300 mg/m3) OEL-GERMANY:TWA 200 ppm (2
60 mg/m3);Skin OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN9 OEL
-JAPAN:TWA 200 ppm (260 mg/m3);Skin OEL-THE NETHERLANDS:TWA 200 ppm (
260 mg/m3);Skin OEL-THE PHILIPPINES:TWA 200 ppm (260 mg/m3) OEL-POLA
ND:TWA 100 mg/m3 OEL-RUSSIA:TWA 200 ppm;STEL 5 mg/m3;Skin OEL-SWEDEN
:TWA 200 ppm (250 mg/m3);STEL 250 ppm (350 mg/m3);Skin OEL-SWITZERLAN
D:TWA 200 ppm (260 mg/m3);STEL 400 ppm;Skin OEL-THAILAND:TWA 200 ppm
(260 mg/m3) OEL-TURKEY:TWA 200 ppm (260 mg/m3) OEL-UNITED KINGDOM:TW
A 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL IN BULGARIA, COLOMBIA, JO
RDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM ch
eck ACGI TLV
CAS# 7647-01-0: OEL-AUSTRALIA:TWA 5 ppm (7 mg/m3) OEL-AUSTRIA:TWA 5
ppm (7 mg/m3) OEL-BELGIUM:STEL 5 ppm (7.7 mg/m3) OEL-DENMARK:STEL 5
ppm (7 mg/m3) OEL-FINLAND:STEL 5 ppm (7 mg/m3);Skin OEL-FRANCE:STEL
5 ppm (7.5 mg/m3) OEL-GERMANY:TWA 5 ppm (7 mg/m3) OEL-HUNGARY:STEL
5 mg/m3 OEL-JAPAN:STEL 5 ppm (7.5 mg/m3) OEL-THE NETHERLANDS:TWA 5 p
pm (7 mg/m3) OEL-THE PHILIPPINES:TWA 5 ppm (7 mg/m3) OEL-POLAND:TWA
5 mg/m3 OEL-RUSSIA:STEL 5 ppm (5 mg/m3) OEL-SWEDEN:STEL 5 ppm (8 mg/
m3) OEL-SWITZERLAND:TWA 5 ppm (7.5 mg/m3);STEL 10 ppm (15 mg/m3) OEL
-THAILAND:TWA 5 ppm (7 mg/m3) OEL-TURKEY:TWA 5 ppm (7 mg/m3) OEL-UNI
TED KINGDOM:TWA 5 ppm (7 mg/m3);STEL 5 ppm (7 mg/m3) OEL IN BULGARIA,
COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPOR
E, VIETNAM check ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #2 Date: 8/02/2000
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.