Material Safety Data
Sheet
Oxalic acid, 0.1 N standard solution
ACC# 97193
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Oxalic acid, 0.1 N standard solution
Catalog
Numbers: AC124280000, AC124280010
Synonyms: Ethanedioic acid
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn,
NJ 07410
For information in North America, call:
800-ACROS-01
For emergencies in the US, call CHEMTREC:
800-424-9300
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 144-62-7 |
Oxalic acid |
<5.0 |
205-634-3 |
| 7732-18-5 |
Water |
Balance |
231-791-2 |
Hazard
Symbols: XN
Risk Phrases: 21/22
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: clear, colorless. Caution! May cause kidney
damage. May cause central nervous system effects. May cause eye and skin
irritation. May cause respiratory and digestive tract irritation. May cause
cyanosis with bluish skin.
Target Organs: Kidneys.
Potential Health Effects
Eye: May cause eye irritation. May result in corneal
injury.
Skin: Causes skin irritation. May cause irritation
with pain and stinging, especially if the skin is abraded.
Ingestion: May cause irritation of the digestive tract.
Inhalation: May cause kidney damage. Exposure may lead to
shock, convulsions, and collapse.
Chronic: No information
found.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin: Get medical aid if irritation develops
or persists. Flush skin with plenty of soap and water.
Ingestion: Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Get medical aid immediately. Remove from
exposure to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
Notes to
Physician: Treat symptomatically and supportively.
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Section 5 -
Firefighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear.
Extinguishing Media: In case of fire, use water, dry
chemical, chemical foam, or alcohol-resistant foam.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spill with inert material,
(e.g., dry sand or earth), then place into a chemical waste container.
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Section 7 - Handling
and Storage |
Handling: Not available.
Storage: Not available.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate general or local exhaust ventilation to keep
airborne concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Oxalic acid |
1 mg/m3; 2 mg/m3 STEL |
1 mg/m3 TWA 500 mg/m3 IDLH |
1 mg/m3 TWA |
| Water |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Oxalic
acid: 1 mg/m3 TWA Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves
and clothing to prevent skin exposure.
Clothing: Wear
appropriate protective clothing to minimize contact with skin.
Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved
full-facepiece airline respirator in the positive pressure mode with emergency
escape provisions.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Not available.
Appearance: clear, colorless
Odor: None
reported.
pH: Not available.
Vapor Pressure: Not
available.
Vapor Density: Not available.
Evaporation
Rate:Not available.
Viscosity: Not available.
Boiling
Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Autoignition
Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:Not
available.
Upper: Not available.
Solubility: soluble in
water
Specific Gravity/Density:.9900g/cm3
Molecular
Formula:C2H2O4
Molecular Weight:90.04
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products: Carbon
monoxide, carbon dioxide.
Hazardous Polymerization: Has not been
reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 144-62-7: RO2450000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 144-62-7:
Oral, rat: LD50 = 7500 mg/kg;
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 144-62-7: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data
available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data
available.
Other Studies: No data available.
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Section 12 -
Ecological Information |
Ecotoxicity: Not
available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
|
US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
|
|
| No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 144-62-7 is listed on the TSCA
inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health
& Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals
in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New
Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this
material have an RQ.
Section 302 (TPQ)
None of the chemicals in
this product have a TPQ.
SARA Codes
CAS # 144-62-7: acute,
chronic, flammable.
Section 313
No chemicals are reportable under
Section 313.
Clean Air Act:
This material does not contain any
hazardous air pollutants. This material does not contain any Class 1 Ozone
depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed
as Hazardous Substances under the CWA. None of the chemicals in this product are
listed as Priority Pollutants under the CWA. None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None
of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 144-62-7 can be found on the following state right to
know lists: California, New Jersey, Florida, Pennsylvania, Minnesota,
Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals
in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
XN
Risk Phrases:
R
21/22 Harmful in contact with skin and if swallowed.
Safety
Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water
Danger/Protection)
CAS# 144-62-7: 1
CAS# 7732-18-5: No information
available.
Canada
CAS# 144-62-7 is listed on Canada's DSL/NDSL
List.
CAS# 7732-18-5 is listed on Canada's DSL/NDSL List.
WHMIS: Not
available.
CAS# 144-62-7 is not listed on Canada's Ingredient Disclosure
List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 144-62-7: OEL-ARAB Republic of Egypt:TWA 1
mg/m3 OEL-AUSTRALIA
:TWA 1 mg/m3;STEL 2 mg/m3 OEL-BELGIUM:TWA 1 mg/m3;STEL 2
mg/m3 OEL-D
ENMARK:TWA 1 mg/m3 OEL-FINLAND:TWA 1 mg/m3;STEL 3 mg/m3
OEL-FRANCE:T
WA 1 mg/m3 OEL-THE NETHERLANDS:TWA 1 mg/m3 OEL-THE
PHILIPPINES:TWA 1
mg/m3 OEL-SWITZERLAND:TWA 1 mg/m3 OEL-UNITED KINGDOM:TWA 1
mg/m3;ST
EL 2 mg/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
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Section 16 -
Additional Information |
MSDS Creation Date:
12/12/1997
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no way
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.