Material Safety Data Sheet
Methylamine, 40 wt. % solution in water

ACC# 00983
Section 1 - Chemical Product and Company Identification
MSDS Name: Methylamine, 40 wt. % solution in water
Catalog Numbers: AC126230000, AC126230010, AC126230025, AC126235000
Synonyms:
Aminomethane; Methanamine; Monomethylamine.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
74-89-5 Methylamine 40 200-820-0
7732-18-5 Water 60 231-791-2

Hazard Symbols:
F C
Risk Phrases:
11 20/22 34

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless. Flash Point: -18 deg C. Danger! May cause liver damage. May cause lung damage. Corrosive. Causes eye and skin burns. May cause respiratory and digestive tract burns. Harmful if inhaled or swallowed. Extremely flammable liquid and vapor. Vapor may cause flash fire. May be harmful if absorbed through the skin.
Target Organs: Liver, respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye burns. May result in corneal injury. May cause chemical conjunctivitis and corneal damage. May cause tearing, conjunctivitis and corneal edema when vapor is absorbed into the tissue of the eye.
Skin: Causes skin burns. May be absorbed through the skin. May cause dermatitis. Methylamine is readily absorbed through the skin and may cause malaise , discomfort, injury and death unless treated promptly.
Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation: Causes chemical burns to the respiratory tract. May cause pulmonary edema and severe respiratory disturbances. May cause liver abnormalities. Inhalation of methylamine may cause coughing, nausea and pulmonary ede ma. Allergic or chemical bronchitis was reported in a worker exposed t o methylamine in an unpublished report. It is unclear from this report what the actual exposure concentrations were.
Chronic: Effects may be delayed. Repeated or prolonged exposure may result in liver disorders and/or ad verse effects to respiratory system (like bronchopneumonia), eyes, or skin. Exposure in test animals has caused liver toxicity and abnormali ties in blood chemistry and lungs.

Section 4 - First Aid Measures


Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse.
Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Runoff to sewer may create fire or explosion hazard. Extremely flammable liquid and vapor. Vapor may cause flash fire. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media: Use water spray, dry chemical, or "alcohol resistant" foam.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as saw dust. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Approach spill from upwind. Use only non-sparking tools and equipment. Use water spray to cool and disperse vapors, protect personnel, and dilute spills to form nonflammable mixtures. 5% sulfuric acid may be used to neutralize diluted pools.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor. Use only with adequate ventilation. Keep away from heat, sparks and flame. Pipes, fittings, pumps, gauges, and other equipment should be made of steel or other material not subject to corrosion by methylamine. Methylamine may attack aluminum, copper, tin, zinc, lead and their alloys as well as rubber and some plastics.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Keep away from acids.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Ventilation fans and other electrical service must be non-sparking and have an explosion-proof design.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Methylamine 5 ppm TWA; 15 ppm STEL 10 ppm TWA; 12 mg/m3 TWA 100 ppm IDLH 10 ppm TWA; 12 mg/m3 TWA
Water none listed none listed none listed

OSHA Vacated PELs: Methylamine: 10 ppm TWA; 12 mg/m3 TWA Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless
Odor: fishy ammonical
pH: >base than ammonia
Vapor Pressure: 485 mm Hg @20 deg C
Vapor Density: 1.07 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 48 deg C @ 760 mm Hg
Freezing/Melting Point:-38 deg C
Autoignition Temperature: 430 deg C ( 806.00 deg F)
Flash Point: -18 deg C ( -0.40 deg F)
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 3; Reactivity: 0
Explosion Limits, Lower:4.90 vol %
Upper: 20.70 vol %
Solubility: Soluble.
Specific Gravity/Density:.9000g/cm3
Molecular Formula:CH5N
Molecular Weight:31.06

Section 10 - Stability and Reactivity


Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Ignition sources, excess heat, attacks aluminum, copper, lead, tin, zinc and alloys.
Incompatibilities with Other Materials: Nitromethane, acids, oxidizing agents, chlorine, hypochlorite, halogenated agents, mercury, copper, copper alloys, zinc, zinc alloys, aluminum, perchlorates.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia and/or derivatives, amines.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:
CAS# 74-89-5: PF6300000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 74-89-5:
Inhalation, mouse: LC50 = 2400 mg/m3/2H;
Inhalation, rat: LC50 = 448 ppm/2.5H;
Oral, rat: LD50 = 100 mg/kg;
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 74-89-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Neurotoxicity: No information found.
Mutagenicity: Mutagenic effects have occurred in experimental animals.
Other Studies: See actual entry in RTECS for complete information.

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: Exists in soil and water mainly in the protonated form. Expected to adsorb to clay and organic carbons in soil and suspended solids and sediment in water. Will biodegrade and not expected to bioconcentrate. Will exist solely in the gas phase in the atmosphere, and will be degraded by photochemically produced hydroxyl radicals (half-life = 18h).
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: METHYLAMINE, AQUEOUS SOLUTION METHYLAMINE, AQUEOUS SOLUTION
Hazard Class: 3 3(9.2)
UN Number: UN1235 UN1235
Packing Group: II II
Additional Info: FLASHPOINT -18 C

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 74-89-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
CAS# 74-89-5: final RQ = 100 pounds (45.4 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 74-89-5: acute, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 74-89-5 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 74-89-5 is considered highly hazardous by OSHA.
STATE
CAS# 74-89-5 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F C
Risk Phrases:

R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 34 Causes burns.

Safety Phrases:

S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 3 Keep in a cool place.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).

WGK (Water Danger/Protection)

CAS# 74-89-5: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 74-89-5 is listed on Canada's DSL List. CAS# 74-89-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.

This product has a WHMIS classification of B2, D1B, E.
CAS# 74-89-5 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 74-89-5: OEL-AUSTRALIA:TWA 10 ppm (12 mg/m3) OEL-BELGIUM:TWA 1
0 ppm (13 mg/m3) OEL-DENMARK:TWA 10 ppm (12 mg/m3) OEL-FINLAND:STEL
10 ppm (12 mg/m3);Skin OEL-FRANCE:STEL 10 ppm (12 mg/m3) OEL-GERMANY
:TWA 10 ppm (12 mg/m3) OEL-JAPAN:TWA 10 ppm (13 mg/m3) OEL-THE NETHE
RLANDS:TWA 10 ppm (12 mg/m3) OEL-THE PHILIPPINES:TWA 10 ppm (12 mg/m3
) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:TWA 10 ppm;STEL 1 mg/m3;Skin OE
L-SWEDEN:TWA 10 ppm (13 mg/m3);STEL 20 ppm (25 mg/m3);Skin OEL-SWITZE
RLAND:TWA 10 ppm (12 mg/m3);STEL 20 ppm (24 mg/m3) OEL-UNITED KINGDOM
:TWA 10 ppm (12 mg/m3) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check
ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #7 Date: 7/16/2001
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.