MSDS Name: Iodine Solutions 1N and Lugol
Catalog Numbers: S71311, S71312, S75056, S75056-1, NC9803180, S750561, SI102-500, SI78-500
Synonyms: None
Company Identification:
              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation.
Storage: Store in a cool, dry place.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Iodine	C 0.1 ppm	2 ppm IDLH	C 0.1 ppm; C 1 mg/m3
Potassium iodide	none listed	none listed	none listed
Water	none listed	none listed	none listed

OSHA Vacated PELs: Iodine: C 0.1 ppm; C 1 mg/m3 Potassium iodide: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: dark amber
Odor: iodine-like
pH: Not available.
Vapor Pressure: 14 mm Hg
Vapor Density: 0.7
Evaporation Rate:>1
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble in water.
Specific Gravity/Density:1.0
Molecular Formula:Not applicable.
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Powdered aluminum, active metals, strong reducing agents. Acetylene and acetaldehyde causes explosive reactions with iodine. Mixtures with ammonium hydroxide form shock sensitive compounds.
Hazardous Decomposition Products: Hydrogen iodide, iodine, iodide ions (I-).
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:
CAS# 7553-56-2: NN1575000
CAS# 7681-11-0: TT2975000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 7553-56-2:
Oral, mouse: LD50 = 22 gm/kg;
Oral, rabbit: LD50 = 10 gm/kg;
Oral, rat: LD50 = 14 gm/kg;
CAS# 7681-11-0:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 7553-56-2: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7681-11-0: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: Potassium iodide has been observed to cause developmental abnormalities of the endocrine system in human fetuses.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	CORROSIVE LIQUIDS, N.O.S. (CONTAINS IODINE)				CORROSIVE LIQUID NOS (IODINE SOLUTION)
Hazard Class:	8				8(9.2)
UN Number:	UN1760				UN1760
Packing Group:	III				III

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7553-56-2 is listed on the TSCA inventory.
CAS# 7681-11-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7553-56-2: acute, chronic, flammable. CAS # 7681-11-0: acute, chronic.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7553-56-2 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 7681-11-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.

Safety Phrases:
S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)
CAS# 7553-56-2: 1
CAS# 7681-11-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7553-56-2 is listed on Canada's DSL List. CAS# 7553-56-2 is listed on Canada's DSL List. CAS# 7681-11-0 is listed on Canada's DSL List. CAS# 7681-11-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.


This product has a WHMIS classification of D2A, E.
CAS# 7553-56-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7681-11-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7553-56-2: OEL-ARAB Republic of Egypt:TWA 0.1 ppm (0.1 mg/m3)
OEL-AUSTRALIA:TWA 0.1 ppm (1 mg/m3) OEL-BELGIUM:STEL 0.1 ppm (1 mg/m3
) OEL-DENMARK:.STEL 1 ppm (1 mg/m3) OEL-FINLAND:STEL 0.1 ppm (1 mg/m
3);Skin OEL-FRANCE:STEL 0.1 ppm (1 mg/m3) OEL-GERMANY:TWA 0.1 ppm (1
mg/m3) OEL-HUNGARY:TWA 1 mg/m3;STEL 2 mg/m3 OEL-JAPAN:TWA 0.1 ppm (
1 mg/m3);STEL 1 mg/m3 JAN9 OEL-THE NETHERLANDS:TWA 0.1 ppm (1 mg/m3)
OEL-THE PHILIPPINES:TWA 0.1 ppm (1 mg/m3) OEL-POLAND:TWA 1 mg/m3 OE
L-RUSSIA:TWA 0.1 ppm;STEL 1 mg/m3;Skin OEL-SWEDEN:STEL 0.1 ppm (1 mg/
m3) OEL-SWITZERLAND:TWA 0.1 ppm (1 mg/m3);STEL 0.2 pp (2 mg/m3) OEL-
THAILAND:TWA 0.1 ppm (1 mg/m3) OEL-TURKEY:TWA 0.1 ppm (1 mg/m3) OEL-
UNITED KINGDOM:STEL 0.1 ppm (1 mg/m3) OEL IN BULGARIA, COLOMBIA, JORD
AN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM chec
k ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 12/12/1997
Revision #2 Date: 8/02/2000
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.