Material Safety Data
Sheet
Glycine
ACC# 10490
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Glycine
Catalog
Numbers: AC9544669, ACE200, S80028, BP381 1, BP381 5, BP381 500,
BP381-1, BP381-5, BP381-500, BP3811, BP3815, BP381500, G46 1, G46 500, G46-1,
G46-500, G461, G4612KG, G46500, G48, G48-20, G48-4, G48-500, G48200LB, G48212,
G48500, G4912, G49212, NC952489, XXG4612KGX
Synonyms: Aminoacetic
Acid; Aminoethanoic Acid.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 56-40-6 |
GLYCINE |
>98% |
200-272-2 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Caution! May be absorbed through intact
skin. May cause eye and skin irritation. May cause respiratory and digestive
tract irritation.
Target Organs: No data found.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. Low hazard for usual
industrial handling. May be absorbed through the skin.
Ingestion: Ingestion of large amounts may cause
gastrointestinal irritation. Low hazard for usual industrial handling.
Inhalation: May cause respiratory tract irritation. Low
hazard for usual industrial handling.
Chronic: No
information found.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid if irritation develops or persists.
Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion: Get medical aid. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid.
Notes to Physician: Treat
symptomatically and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Dusts at sufficient concentrations can form explosive mixtures with air.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media: Use agent
most appropriate to extinguish fire. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up, then place
into a suitable container for disposal. Avoid generating dusty conditions.
Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| GLYCINE |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: GLYCINE:
No OSHA Vacated PELs are listed for this chemical.
Personal
Protective Equipment
Eyes: Wear appropriate
protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to
prevent skin exposure.
Respirators: A respiratory protection program
that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace conditions warrant a
respirator's use.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: none reported
pH:
4.0 (1.4% sol.)
Vapor Pressure: Negligible.
Vapor Density:
Not available.
Evaporation Rate:Negligible.
Viscosity: Not
available.
Boiling Point: Not available.
Freezing/Melting
Point:504 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:504
deg F
NFPA Rating: (estimated) Health: 1; Flammability: 0;
Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: 25 g/100ml (25 C) in
water.
Specific Gravity/Density:1.6 (water=1)
Molecular
Formula:C2H5NO2
Molecular Weight:75.0405
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide,
irritating and toxic fumes and gases, carbon dioxide.
Hazardous
Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 56-40-6: MB7600000
LD50/LC50:
CAS#
56-40-6:
Oral, mouse: LD50 = 4920 mg/kg;
Oral, rat: LD50 = 7930
mg/kg;
Carcinogenicity:
CAS# 56-40-6: Not listed by ACGIH,
IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Neurotoxicity: No information
available.
Mutagenicity: No information available.
Other
Studies: See actual entry in RTECS for complete information.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 56-40-6 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 56-40-6 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals
in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 56-40-6: 0
Canada
CAS# 56-40-6 is
listed on Canada's DSL List. CAS# 56-40-6 is listed on Canada's DSL List.
This product has a WHMIS classification of Not controlled..
CAS# 56-40-6
is not listed on Canada's Ingredient Disclosure List.
Exposure
Limits
CAS# 56-40-6: OEL-RUSSIA:STEL 5 mg/m3
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Section 16 -
Additional Information |
MSDS Creation Date:
7/13/1999
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.