Material Safety Data
Sheet
Bromocresol Green
ACC# 60160
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Bromocresol Green
Catalog Numbers: S71379, S71380, B383 5, B383-5, B3835,
V0146
Synonyms: BCG; Bromcresol blue; M-cresol
4,4'-(3H-2,1-benzoxathiol-3-ylidene)bis(2,6-dibromo-s,s-dioxide;
Company
Identification:
Fisher
Scientific
1 Reagent
Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For
International CHEMTREC assistance, call: 703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 76-60-8 |
Bromocresol green |
ca. 100 |
200-972-8 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: beige to brown. Caution! May cause eye and skin
irritation. May cause respiratory and digestive tract irritation. The
toxicological properties of this material have not been fully investigated.
Target Organs: None known.
Potential Health
Effects
Eye: Dust may cause mechanical
irritation. This product contains an anionic dye. Similar dyes have not caused
injury to the cornea or conjunctiva in documented exposure cases with human or
rabbit eyes.
Skin: May cause skin irritation. No
information regarding skin irritation and other potential effects was found.
Ingestion: May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. The toxicological properties of this substance
have not been fully investigated.
Inhalation: May cause
respiratory tract irritation. The toxicological properties of this substance
have not been fully investigated.
Chronic: May be harmful
if ingested in large amounts.
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Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Get medical aid. Flush skin with plenty
of soap and water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion: Induce
vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid.
Notes to Physician: Treat
symptomatically and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant
foam. Use agent most appropriate to extinguish fire.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances. Keep
containers tightly closed.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Bromocresol green |
none listed |
none listed |
none
listed |
OSHA Vacated PELs:
Bromocresol green: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear appropriate
protective clothing to minimize contact with skin.
Respirators: A
respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2
requirements or European Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Crystalline powder
Appearance: beige to brown
Odor:
odorless
pH: Not available.
Vapor Pressure: Not
applicable.
Vapor Density: Not available.
Evaporation
Rate:Not applicable.
Viscosity: Not applicable.
Boiling
Point: Not applicable.
Freezing/Melting Point:225 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not
applicable.
Decomposition Temperature:225 deg C
NFPA
Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not
available.
Solubility: Slightly soluble in water.
Specific
Gravity/Density:Not available.
Molecular Formula:C21H14Br4O5S
Molecular Weight:698.04
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, oxides of sulfur,
irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Will not occur.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 76-60-8: SJ7456000
LD50/LC50:
Not
available.
Carcinogenicity:
CAS# 76-60-8: Not listed by ACGIH,
IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Neurotoxicity: No information
available.
Mutagenicity: No information available.
Other
Studies: No data available.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 76-60-8 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 76-60-8 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals
in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 76-60-8: No information available.
Canada
CAS# 76-60-8 is listed on Canada's DSL List. CAS# 76-60-8
is listed on Canada's DSL List.
This product has a WHMIS classification of
D2B.
CAS# 76-60-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
3/22/1999
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.