MSDS Name: Zinc Metal (Shot, Pieces and Sheet)
Catalog Numbers: S71226-3, S71226-4, S71226-5, S712264, S712265, Z12 500, Z12500
Synonyms: None
Company Identification:
              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid if irritation develops or persists. Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically.
Antidote: The use of Calcium disodium EDTA as a chelating agent should be determined by qualified medical personnel.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. May ignite or explode on contact with steam or moist air.
Extinguishing Media: Use dry sand or earth to smother fire. DO NOT USE WATER! Do NOT get water inside containers. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not expose spill to water.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not allow water to get into the container because of violent reaction. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage: Store in a cool, dry place. Keep away from water. Keep containers tightly closed.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use explosion-proof ventilation equipment. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Zinc	none listed	none listed	none listed

OSHA Vacated PELs: Zinc: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - Physical and Chemical Properties

Physical State: Solid
Appearance: grey
Odor: odorless
pH: Not available.
Vapor Pressure: 1 mm Hg @ 487C
Vapor Density: Not available.
Evaporation Rate:Not applicable
Viscosity: Not applicable
Boiling Point: 908 deg C
Freezing/Melting Point:419 deg C
Autoignition Temperature: 460 deg C ( 860.00 deg F)
Flash Point: Not available.
Decomposition Temperature:Not available.
NFPA Rating:
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Reacts with water
Specific Gravity/Density:7.14
Molecular Formula:Zn
Molecular Weight:65.38

Section 10 - Stability and Reactivity

Chemical Stability: Stable. Combines vigorously or explosively with water.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, exposure to moist air or water, mechanical shock.
Incompatibilities with Other Materials: Halogenated agents, strong oxidizing agents, alkali hydroxides.
Hazardous Decomposition Products: Toxic fumes of zinc oxide.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information

RTECS#:
CAS# 7440-66-6: ZG8600000
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 7440-66-6: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: No data available.

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	No information available.				No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7440-66-6 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 7440-66-6: 6a/12b
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
CAS# 7440-66-6: final RQ = 1000 pounds (454 kg) (no reporting of releases of this hazardous
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7440-66-6: acute.
Section 313
This material contains Zinc (CAS# 7440-66-6, 100%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. CAS# 7440-66-6 is listed as a Priority Pollutant under the Clean Water Act. CAS# 7440-66-6 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7440-66-6 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F
Risk Phrases:
R 15 Contact with water liberates highly flammable
gases.
R 17 Spontaneously flammable in air.

Safety Phrases:

WGK (Water Danger/Protection)
CAS# 7440-66-6: 0
Canada
CAS# 7440-66-6 is listed on Canada's DSL List. CAS# 7440-66-6 is listed on Canada's DSL List.
This product has a WHMIS classification of D2B.
CAS# 7440-66-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7440-66-6: OEL-ARAB Republic of Egypt:TWA 0.1 mg/m3

Section 16 - Additional Information

MSDS Creation Date: 4/09/1998
Revision #3 Date: 8/23/2000
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.