MSDS Name: Tin (II) Chloride Dihydrate
Catalog Numbers: S80206, S80206-1, S802061, T142 100, T142 3, T142 500, T142-100, T142-3, T142-500, T142100, T1423, T142500, T163 250, T163 500, T163-250, T163-500, T163250, T163500
Synonyms: Stannous chloride dihydrate; Stannochlor; Stannous chloride dihydrate
Company Identification:
              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 4 - First Aid Measures

Eyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Storage: Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Tin (II) Chloride Dihydrate	none listed	none listed	none listed

OSHA Vacated PELs: Tin (II) Chloride Dihydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties

Physical State: Solid
Appearance: colorless to white
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not applicable.
Evaporation Rate:negligible
Viscosity: Not available.
Boiling Point: decomposes
Freezing/Melting Point:100 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: decomposes in water
Specific Gravity/Density:2.7
Molecular Formula:SnCl2.2H2O
Molecular Weight:225.6228

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials, moisture, exposure to air.
Incompatibilities with Other Materials: Moisture.
Hazardous Decomposition Products: Hydrogen chloride, chlorine, irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information

RTECS#:
CAS# 10025-69-1: XP8850000
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 10025-69-1: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: Oral, rat: TDLo = 3 gm/kg (female 7-12 day(s) after conception) Effects on Embryo or Fetus - fetal death.; Oral, rat: TDLo = 3 gm/kg (female 7-12 day(s) after conception) Specific Developmental Abnormalities - craniofacial (including nose and tongue).
Reproductive Effects: Oral, rat: TDLo = 3 gm/kg (female 7-12 day(s) after conception) Maternal Effects - other effects and Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants). Reproductive - Effects on Embryo or Fetus - fetal death
Neurotoxicity: No data available.
Mutagenicity: DNA Damage: Human, Leukocyte = 10 umol/L.; DNA Damage: Hamster, Ovary = 50 umol/L.
Other Studies: No data available.

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	CORROSIVE SOLID, N.O.S. (STANNOUS CHLORIDE)				CORROSIVE SOLID NOS (STANNOUS CHLORIDE)
Hazard Class:	8				8(9.2)
UN Number:	UN1759				UN1759
Packing Group:	III				III

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 10025-69-1 is not on the TSCA Inventory. It is a hydrate and exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10025-69-1: acute, chronic, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 10025-69-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.

Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.

WGK (Water Danger/Protection)
CAS# 10025-69-1: No information available.
Canada
Canada

None of the chemicals in this product are listed on the DSL or NDSL list. This product has a WHMIS classification of E, D2A.
CAS# 10025-69-1 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10025-69-1: OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 OEL-BELGIUM:TWA 2 mg
(Sn)/m3 OEL-DENMARK:TWA 2 mg(Sn)/m3 OEL-FINLAND:TWA 2 mg(Sn)/m3 OEL
-GERMANY:TWA 2 mg(Sn)/m3 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3
;Skin OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 OEL-THE PHILIPPINES:TWA 2
mg(Sn)/m3 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 OEL-THAIL
AND:TWA 2 mg(Sn)/m3 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)
/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN
NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 6/25/1999
Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.