Material Safety Data
Sheet
Sodium Acetate Trihydrate
ACC# 20865
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium Acetate Trihydrate
Catalog Numbers: S78229, BP334-1, BP334-500, CRNS209-10,
NC9573934, S207-10, S209-10, S209-10LC, S209-3, S209-500, S20950, S220-1,
S608-12, S608-3, S608-50, S608-500, S609-100, S609-12, S609-212, S609-25,
S609-500
Synonyms: Acetic acid, sodium salt, trihydrate.
Company Identification:
Fisher Scientific
1
Reagent Lane
Fair Lawn, NJ
07410
For information, call: 201-796-7100
Emergency
Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 127-09-3 |
Sodium acetate anhydrous |
- |
204-823-8 |
| 6131-90-4 |
Sodium acetate trihydrate |
100 |
unlisted
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Hazard Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Caution! May cause eye and skin
irritation. Hygroscopic. May cause respiratory tract irritation.
Target Organs: None.
Potential Health
Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: Ingestion of large amounts may cause
gastrointestinal irritation.
Inhalation: No hazard expected
in normal industrial use.
Chronic: No information found.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion: If victim is
conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid if cough or other symptoms appear.
Notes to
Physician: None
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Combustion generates toxic fumes.
Extinguishing
Media: For small fires, use water spray, dry chemical, carbon dioxide
or chemical foam.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation.
Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage: Keep from contact with oxidizing materials. Store
in a cool, dry, well-ventilated area away from incompatible substances. Store
protected from moisture.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Good general ventilation should be sufficient to control
airborne levels.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Sodium acetate anhydrous |
none listed |
none listed |
none listed |
| Sodium acetate trihydrate |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Sodium
acetate anhydrous: No OSHA Vacated PELs are listed for this chemical. Sodium
acetate trihydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear safety glasses with side shields.
Skin: Wear
appropriate gloves to prevent skin exposure.
Clothing: Wear
appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN
149 approved respirator when necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: odorless
pH: 8.9
(0.1M Solution)
Vapor Pressure: Not available.
Vapor
Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 253 deg F
Freezing/Melting Point:136 deg F
Autoignition Temperature:
599 deg C ( 1,110.20 deg F)
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 1; Reactivity: 0
Explosion Limits,
Lower:Not available.
Upper: Not available.
Solubility:
Soluble in water, ether
Specific Gravity/Density:1.45
Molecular Formula:C2H3O2Na.3H2O
Molecular Weight:136.08
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable.
Conditions to Avoid: Exposure to moist air or
water.
Incompatibilities with Other Materials: Strong oxidizers
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 127-09-3: AJ4300010
CAS# 6131-90-4: AJ4580000
LD50/LC50:
CAS# 127-09-3:
Draize test, rabbit, eye: 10 mg
Mild;
Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, rat: LC50 =
>30 gm/m3/1H;
Oral, mouse: LD50 = 6891 mg/kg;
Oral, rat: LD50 = 3530
mg/kg;
Skin, rabbit: LD50 = >10 gm/kg;
CAS# 6131-90-4:
Carcinogenicity:
CAS# 127-09-3: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA. CAS# 6131-90-4: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No
information available.
Reproductive Effects: No information
available.
Neurotoxicity: No information available.
Mutagenicity: Mutagenic effects have occurred in experimental
animals.
Other Studies: No data available.
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Section 12 -
Ecological Information |
Ecotoxicity: No
data available. Acute aquatic effects (for anhydrous sodium acetate)96-hour
LC50; Fathead minnow: GT 100 mg/L 96-hour LC50; Water flea: GT 1000 mg/L.This
chemical has a high biological oxygen demand, and it is expected to cause
significant oxygen depletion in aquatic systems. It has a low potential to
affect aquatic organisms.
Environmental: This chemical is readily
biodegradable and is not likely to bioconcentrate.
Physical: None
reported
Other: None
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 127-09-3 is listed on the TSCA
inventory.
CAS# 6131-90-4 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
Health &
Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals
in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New
Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this
material have an RQ.
Section 302 (TPQ)
None of the chemicals in
this product have a TPQ.
SARA Codes
CAS # 6131-90-4.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 127-09-3 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
CAS# 6131-90-4 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals
in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin
and eyes.
WGK (Water Danger/Protection)
CAS# 127-09-3: 1
CAS# 6131-90-4: 1
Canada
CAS# 127-09-3 is listed on Canada's
DSL List. CAS# 127-09-3 is listed on Canada's DSL List. CAS# 127-09-3 is listed
on Canada's DSL List.
This product has a WHMIS classification of Not
controlled..
CAS# 127-09-3 is not listed on Canada's Ingredient Disclosure
List.
CAS# 6131-90-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
7/12/1999
Revision #2 Date: 8/14/2001
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.