Material Safety Data
Sheet
Sodium Hydride, 60% Dispersion in Mineral Oil, DMF Soluble Bags
ACC# 97730
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium Hydride, 60% Dispersion in Mineral Oil, DMF
Soluble Bags
Catalog Numbers: AC302650000, AC302651000, AC302652500
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America,
call: 800-ACROS-01
For emergencies in the US, call CHEMTREC:
800-424-9300
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7646-69-7 |
SODIUM HYDRIDE |
60% |
231-587-3 |
| 8042-47-5 |
MINERAL OIL |
40% |
232-455-8 |
Hazard
Symbols: F
Risk Phrases: 15
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white to gray. Caution! Water-Reactive. May
cause severe respiratory and digestive tract irritation with possible burns. May
cause severe eye and skin irritation with possible burns. Dangerous when wet.
Target Organs: None.
Potential Health
Effects
Eye: May cause eye irritation and
possible burns.
Skin: May cause severe skin irritation with
possible burns, especially if skin is wet or moist.
Ingestion: May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns.
Inhalation: May cause severe irritation of the respiratory
tract with possible burns.
Chronic: None
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Never give anything by mouth to an unconscious
person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse
mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
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Section 5 -
Firefighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Water Reactive. Material will react with water and may release a flammable
and/or toxic gas. Containers may explode in the heat of a fire. May re-ignite
after fire is extinguished.
Extinguishing Media: Do NOT get
water inside containers. Cool containers with flooding quantities of water until
well after fire is out. DO NOT USE WATER OR FOAM. For small fires, use dry
chemical, soda ash, lime or sand. For large fires, use dry sand, dry chemical,
soda ash or lime or withdraw from area and let fire burn.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spill with inert material,
(e.g., dry sand or earth), then place into a chemical waste container. Provide
ventilation. Do not expose spill to water. Do not get water inside containers.
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Section 7 - Handling
and Storage |
Handling: Avoid breathing dust, vapor, mist, or gas.
Avoid contact with skin and eyes. Do not allow contact with water. Use only in a
chemical fume hood.
Storage: Keep away from sources of
ignition. Store in a cool, dry place. Store in a tightly closed container. Water
free area. Store totally immersed in oil.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| SODIUM HYDRIDE |
none listed |
none listed |
none listed |
| MINERAL OIL |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: SODIUM
HYDRIDE: No OSHA Vacated PELs are listed for this chemical. MINERAL OIL: No OSHA
Vacated PELs are listed for this chemical.
Personal Protective
Equipment
Eyes: Wear appropriate protective
eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to
prevent skin exposure.
Respirators: Follow the OSHA respirator
regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid/Liquid Mixture
Appearance: white to gray
Odor:
Practically odorless
pH: Not available.
Vapor Pressure:
Not available.
Vapor Density: Not available.
Evaporation
Rate:Not available.
Viscosity: Not available.
Boiling
Point: Not available.
Freezing/Melting Point:800 deg C
Decomposition Temperature:> 225 deg C
Autoignition
Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:N/A
Upper: N/A
Solubility: Reacts.
Specific
Gravity/Density:1.2000g/cm3
Molecular Formula:HNa
Molecular Weight:23.9968
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Not available.
Conditions to Avoid: Incompatible
materials, exposure to air, contact with water, temperatures above 220°C.
Incompatibilities with Other Materials: Acids - alcohols - carbon
dioxide - hydrogenhalides.
Hazardous Decomposition Products: Carbon
monoxide, carbon dioxide, hydrogen gas.
Hazardous Polymerization: Has
not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 7646-69-7: WB3910000
CAS# 8042-47-5: PY8047000
LD50/LC50:
Not available.
Not
available.
Carcinogenicity:
CAS# 7646-69-7: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 8042-47-5: Not listed by ACGIH, IARC,
NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects:
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
available.
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Section 12 -
Ecological Information |
Ecotoxicity: Not
available.
Environmental Fate: Not available.
Physical/Chemical: Not available.
Other: Not available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
|
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| No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7646-69-7 is listed on the TSCA
inventory.
CAS# 8042-47-5 is listed on the TSCA inventory.
Health
& Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals
in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New
Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this
material have an RQ.
Section 302 (TPQ)
None of the chemicals in
this product have a TPQ.
Section 313
No chemicals are reportable
under Section 313.
Clean Air Act:
This material does not contain
any hazardous air pollutants. This material does not contain any Class 1 Ozone
depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed
as Hazardous Substances under the CWA. None of the chemicals in this product are
listed as Priority Pollutants under the CWA. None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None
of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7646-69-7 can be found on the following state right to
know lists: New Jersey, Florida, Pennsylvania, Massachusetts.
CAS# 8042-47-5
is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No
Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in
Accordance with EC Directives
Hazard Symbols:
F
Risk
Phrases:
R 15 Contact with water liberates highly flammable gases.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes. S 7/8
Keep container tightly closed and dry. S 43A In case of fire, use dry chemical
(never use water).
WGK (Water Danger/Protection)
CAS# 7646-69-7: 1
CAS# 8042-47-5: No information available.
Canada
CAS#
7646-69-7 is listed on Canada's DSL/NDSL List.
CAS# 8042-47-5 is listed on
Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 7646-69-7 is not
listed on Canada's Ingredient Disclosure List.
CAS# 8042-47-5 is not listed
on Canada's Ingredient Disclosure List.
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
2/05/1998
Revision #2 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no way
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.