Material Safety Data
Sheet
Sodium Sulfate Anhydrous
ACC# 21630
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium Sulfate Anhydrous
Catalog Numbers: S78859, S78859-1, S80193, BP354-500,
BW1366550, NC9517838, NC9518024, NC9569761, NC9581693, NC9614498, NC9671081,
NC9727361, NC9797115, NC9862315, NC9868791, S415-1, S415-10, S415-10S,
S415-200LB, S415-212, S415-3, S415-500, S41510S001, S4151LC, S4151LOT002,
S415200001, S415212001, S415212002, S415LOT002, S418-212, S418-500, S420-10,
S420-3, S421-1, S421-10, S421-3, S421-300LB, S421-50, S421-500, S42110001,
S421300LB, S4213LOT004, S429-12, S429-212, S429-500, S429250LB, S43112, S43412,
S78859-4, XXNASULSM200LB, XXNASULSM50KG, XXS41510KG, XXS415ET2.5KG,
XXS415MB200LB, XXS415MN200LB, XXSODSULFSM10K
Synonyms: Bisodium
sulfate; Dibasic sodium sulfate; Disodium monosulfate; Disodium sulfate;
Natriumsulfate; Sodium sulphate; Sulfuric acid, disodium salt; Thenardite
Company Identification:
Fisher Scientific
1
Reagent Lane
Fair Lawn, NJ
07410
For information, call: 201-796-7100
Emergency
Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7757-82-6 |
Sodium sulfate |
ca.100 |
231-820-9 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Caution! Moisture sensitive. This is
expected to be a low hazard for usual industrial handling. May cause eye and
skin irritation. May cause respiratory and digestive tract irritation. May cause
fetal effects based upon animal studies.
Target Organs: No
data found.
Potential Health
Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: Ingestion of large amounts may cause
gastrointestinal irritation. Low hazard for usual industrial handling.
Inhalation: May cause respiratory tract irritation. Low
hazard for usual industrial handling.
Chronic: No
information found.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin: Flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated clothing and
shoes. Get medical aid if irritation develops or persists. Wash clothing before
reuse.
Ingestion: Never give anything by mouth to an
unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth
and drink 2-4 cupfuls of milk or water. Get medical aid if irritation or
symptoms occur.
Inhalation: Remove from exposure to fresh
air immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. This material in sufficient quantity and
reduced particle size is capable of creating a dust explosion.
Extinguishing Media: Substance is nonflammable; use agent
most appropriate to extinguish surrounding fire. Do NOT get water inside
containers.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation. Do not get water inside containers.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Wash hands
before eating. Remove contaminated clothing and wash before reuse. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation. Use with adequate ventilation. Do not allow contact
with water. Keep from contact with moist air and steam.
Storage: Keep from contact with oxidizing materials. Store
in a cool, dry, well-ventilated area away from incompatible substances. Do not
store in aluminum containers. Store protected from moisture.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Sodium sulfate |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Sodium
sulfate: No OSHA Vacated PELs are listed for this chemical.
Personal
Protective Equipment
Eyes: Wear appropriate
protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to
prevent skin exposure.
Respirators: A respiratory protection program
that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace conditions warrant a
respirator's use.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Powder
Appearance: white
Odor: odorless
pH: 4.9
(5% solution)
Vapor Pressure: Not available.
Vapor
Density: Not available.
Evaporation Rate:Not available.
Viscosity: 2.48 (22% soln)
Boiling Point: 1100 deg C (dec)
Freezing/Melting Point:880-888 deg C
Autoignition
Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits,
Lower:Not available.
Upper: Not available.
Solubility:
Soluble in cold water.
Specific Gravity/Density:2.671
Molecular Formula:Na2SO4
Molecular Weight:142.0372
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Incompatible
materials, dust generation, moisture, excess heat.
Incompatibilities with
Other Materials: Strong oxidizing agents, aluminum, magnesium, potassium,
mercury, lead, calcium, silver, barium, ammonium ions, strontium.
Hazardous Decomposition Products: Oxides of sulfur, irritating and
toxic fumes and gases, sodium oxide.
Hazardous Polymerization: Will
not occur.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 7757-82-6: WE1650000
LD50/LC50:
CAS#
7757-82-6:
Oral, mouse: LD50 = 5989 mg/kg;
Carcinogenicity:
CAS# 7757-82-6: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA.
Epidemiology: Subcutaneous, mouse: TDLo = 806
mg/kg/26W-I (Tumorigenic - e quivocal tumorigenic agent by RTECS criteria - Skin
and Ap pendages - tumors.
Teratogenicity: Oral, mouse: TDLo = 14
gm/kg (female 8-12 day(s) after conception) Effects on Newborn - other neonatal
measures or effects.; Parenteral, mouse: TDLo = 60 mg/kg (female 8 day(s) after
conception) Effects on Embryo or Fetus - fetotoxicity (except death, e.g.,
stunted fetus) and Specific Developmental Abnormalities - musculoskeletal
system.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity:
Tumorigenic: Subcutaneous, mouse: TDLo = 806 mg/kg/26wks (Skin and appendage
tumors).
Other Studies: See actual entry in RTECS for complete
information.
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Section 12 -
Ecological Information |
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 12,750 ppm; 96 Hr; Static bioassay flea Daphnia:
LC50 = 4547 mg/L; 96 Hr; Unspecified Fathead Minnow: LC50 = 13,500-14,000 mg/L;
24 - 96 Hr; Unspecified Mosquito Fish: LC50 = 17,500 mg/L; 96 Hr; Unspecified
This chemical is not expected to cause oxygen depletion in aquatic systems. It
has a low potential to affect aquatic organisms and is expected to have a low
potential to affect secondary waste treatment microorganisms.
Environmental: Sodium sulfate may persist indefinitely in the
environment, but is not likely to show bioaccumulation or food chain
contamination effects. If diluted with water, this chemical released directly or
indirectly into the environment is not expected to have a significant impact.
Physical: No information available.
Other: This chemical
is not likely to bioconcentrate.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7757-82-6 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7757-82-6 can be found on the following state right to
know lists: Pennsylvania, Massachusetts.
California No Significant Risk
Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in
Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 7757-82-6: 0
Canada
CAS# 7757-82-6
is listed on Canada's DSL List. CAS# 7757-82-6 is listed on Canada's DSL List.
This product has a WHMIS classification of D2A.
CAS# 7757-82-6 is not
listed on Canada's Ingredient Disclosure List.
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
7/15/1999
Revision #2 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.