Material Safety Data
Sheet
Sodium Borate Solution, Borax 1-4%, Buffer pH 9.18
ACC# 75177
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium Borate Solution,
Borax 1-4%, Buffer pH 9.18
Catalog Numbers: LC11710,
LC12450, LC22960
Synonyms: solutions of...borax, borax decahydrate,
buffer pH 9.18 sodium tetraborate, buffer pH 9.18
Company
Identification:
Labchem
Inc.
200 William Pitt
Way
Pittsburgh, PA 15238
For information, call: 412-826-5230
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 1303-96-4 |
Borates, tetra, sodium salts, decahydrate |
1-4 |
unlisted |
| 7732-18-5 |
Water |
balance |
231-791-2 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: colorless. Caution! May cause respiratory and
digestive tract irritation. May cause eye irritation and transient injury.
Target Organs: None known.
Potential Health
Effects
Eye: Causes redness, pain, and
irritation.
Skin: Borates absorbed through the skin
producing skin eruptions, anuria, fever. Skin readily absorbed through damaged,
abraided, burned skin or open wounds; produce system effects as in inhalation.
Ingestion: May produce vomiting, diarrhea, erythroderma
(followed by desquamation, excoriation, blistering, sloughing); lethargy, muscle
twitching, convulsions, hyperpyrexia, jaundice, kidney damage with oliguria,
anuria, cyanosis, hypotension, collapse, and coma. Fatal dose 5-30g.
Inhalation: Causes effects similar to those of acute skin
absorption.
Chronic: Prolonged or repeated eye contact may
cause conjunctivitis. May result in anorexia, weight loss, vomiting, mild
diarrhea, skin rash, convulsions, anemia, alopecia. Skin - prolonged contact may
reslut in inhalation symptoms.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower lids until no evidence of
chemical remains. Get medical aid at once.
Skin: Get
medical aid. Immediately flush skin with plenty of soap and water for at least
15 minutes while removing contaminated clothing and shoes. Remove contaminated
clothing and shoes.
Ingestion: Give conscious victim 2-4
cupfuls of milk or water. Induce vomiting (touch finger to back of throat)
keeping head lower than hips (prevent aspiration into lungs).
Inhalation: Give artificial respiration if necessary. Get
medical aid. Keep victim warm, at rest. Move victim to fresh air.
Notes to Physician: Treat symptomatically and supportively.
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Section 5 -
Firefighting Measures |
General
Information: Negligible fire and explosion hazard when exposed to heat
or flame. Move container if possible, avoid breathing vapors or dust. Acts as
fire retardant when impregnated into combustible materials.
Extinguishing Media: For small fires, use dry chemical,
carbon dioxide, water spray or alcohol-resistant foam.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Absorb spills with absorbent
(vermiculite, sand, fuller's earth) and place in plastic bags for later
disposal. Area may be washed down with water. Larger spills have a herbicidal
effect, keep out of water/sewer.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Avoid
breathing dust, vapor, mist, or gas.
Storage: Store capped
at room temperature. Protect from heat and incompatibles.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Provide local exhaust or general dilution ventilation.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Borates, tetra, sodium salts, decahydrate |
1 mg/m3 (anhydrous); 5 mg/m3 (decahydrate); 1 mg/m3
(pentahydrate) |
5 mg/m3 TWA |
none listed |
| Water |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Borates,
tetra, sodium salts, decahydrate: 10 mg/m3 TWA Water: No OSHA Vacated PELs are
listed for this chemical.
Personal Protective Equipment
Eyes: Do not wear contact lenses when working with
chemicals. An eye wash fountain should be available in the immediate work area.
Wear splash-proof safety goggles.
Skin: Wear appropriate
protective gloves to prevent skin exposure.
Clothing: Wear
appropriate protective clothing to prevent skin exposure.
Respirators: Not required for normal use. Firefighting-- any
self-contained breathing apparatus with full facepiece operated in
pressure-demand mode.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Clear liquid
Appearance: colorless
Odor: odorless
pH: 9.18
Vapor Pressure: Not available.
Vapor
Density: Not available.
Evaporation Rate:< ether
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition
Temperature:Not available.
Autoignition Temperature: Not
available.
Flash Point: Not available.
NFPA Rating: Not
published.
Explosion Limits, Lower:Not available.
Upper:
Not available.
Solubility: Soluble.
Specific
Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.
|
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Incompatible materials.
Incompatibilities with Other
Materials: Not available.
Hazardous Decomposition Products: Toxic
fumes of sodium oxide.
Hazardous Polymerization: Has not been
reported
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 1303-96-4 unlisted.
CAS# 7732-18-5 unlisted.
LD50/LC50:
CAS# 1303-96-4:
Oral, mouse: LD50 = 2
gm/kg;
Oral, rat: LD50 = 2660 mg/kg;
CAS# 7732-18-5:
Oral,
rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 1303-96-4:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: Borate poisoning
affects kidneys; eye, skin, mucous membrane irritant.
Teratogenicity:
No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data
available.
Other Studies: No data available.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 1303-96-4 is listed on the TSCA
inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health
& Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals
in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New
Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this
material have an RQ.
Section 302 (TPQ)
None of the chemicals in
this product have a TPQ.
SARA Codes
CAS # 1303-96-4: chronic.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 1303-96-4 can be found on the following state right to
know lists: California, New Jersey, Florida, Pennsylvania, Minnesota,
Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN,
MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals
in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 1303-96-4: 1
CAS# 7732-18-5: No information
available.
Canada
CAS# 1303-96-4 is listed on Canada's DSL List.
CAS# 1303-96-4 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on
Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.
WHMIS:
Not available.
CAS# 1303-96-4 is listed on Canada's Ingredient Disclosure
List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 1303-96-4: OEL-AUSTRALIA:TWA 5 mg/m3
OEL-BELGIUM:TWA 5 mg/m3
OEL-DENMARK:TWA 5 mg/m3 OEL-FRANCE:TWA 5 mg/m3
OEL-THE NETHERLANDS:T
WA 5 mg/m3 OEL-SWEDEN:TWA 2 mg/m3;STEL 5 mg/m3;Skin
OEL-SWITZERLAND:
TWA 5 mg/m3 OEL-UNITED KINGDOM:TWA 5 mg/m3 OEL IN BULGARIA,
COLOMBIA
, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE,
VIETNA
M check ACGI TLV
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Section 16 -
Additional Information |
MSDS Creation Date:
2/16/1998
Revision #1 Date: 12/06/2000
Information in this MSDS is from
available published sources and is believed to be accurate. No warranty, express
or implied, is made and LabChem Inc. assumes no liability resulting from the use
of this MSDS. The user must determine suitability of this information for his
application.