Material Safety Data Sheet
Manganese (II) Sulfate Monohydrate

ACC# 13655
Section 1 - Chemical Product and Company Identification

MSDS Name: Manganese (II) Sulfate Monohydrate
Catalog Numbers: S80061ACS, S80071-2, M113 3, M113 500, M113-3, M113-500, M1133, M113500, M114-12, M114-212, M114-500, M114212, M114500, M11512, M115212, M115500, NC9747671
Synonyms:
Manganese(II) sulfate, monohydrate, manganous sulfate monohydrate
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
10034-96-5 Manganese sulfate, monohydrate >98 unlisted

Hazard Symbols:
XN
Risk Phrases:
40/20/22

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: pink. Caution! May cause eye and skin irritation. May cause respiratory and digestive tract irritation. May cause central nervous system effects. Hygroscopic.
Target Organs: Central nervous system.


Potential Health Effects
Eye: May cause mild eye irritation.
Skin: May cause skin irritation. Low hazard for usual industrial handling.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause respiratory tract irritation.
Chronic: Chronic inhalation or ingestion may cause argyria characterized by blue-gray discoloration of the eyes, skin and mucous membrances. Chronic skin contact may cause permanent discoloration of the skin.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Remove contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Calcium disodium EDTA as a chelating agent should be determined by qualified medical personnel.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn.
Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - Handling and Storage


Handling: Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Manganese sulfate, monohydrate none listed none listed none listed

OSHA Vacated PELs: Manganese sulfate, monohydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear impervious gloves.
Clothing: Wear appropriate protective gloves and clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: pink
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1562 deg F
Freezing/Melting Point:1292 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:3.25 (water=1)
Molecular Formula:MnSO4.H2O
Molecular Weight:169.009

Section 10 - Stability and Reactivity


Chemical Stability: Stable.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Can react with strong acid, strong oxidizing agents, powdered metals; may react violently with hydrogen peroxide.
Hazardous Decomposition Products: Carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide, oxides of manganese.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:
CAS# 10034-96-5: OP0893500
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 10034-96-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: No information available. No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 10034-96-5 is not on the TSCA Inventory. It is a hydrate and exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10034-96-5: chronic.
Section 313
This material contains Manganese sulfate, monohydrate (listed as ** undefined **), 98%, (CAS# 10034-96-5) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 10034-96-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:

R 40/20/22 Harmful : possible risk of irreversible
effects through inhalation and if swallowed.

Safety Phrases:


WGK (Water Danger/Protection)

CAS# 10034-96-5: 1
Canada
Canada

None of the chemicals in this product are listed on the DSL or NDSL list. This product has a WHMIS classification of D2B.
CAS# 10034-96-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10034-96-5: OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JANUARY 1993 OEL-BE
LGIUM:TWA 5 mg(Mn)/m3 JANUARY 1993 OEL-CZECHOSLOVAKIA:TWA 2 mg(Mn)/m
3;STEL 6 mg(Mn)/m3 JANUARY 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JANUA
RY 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JANUARY 1993 OEL-HUNGARY:TWA
0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JANUARY 1993 OEL-JAPAN:TWA 0.3 mg(Mn
)/m3 JANUARY 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JANUARY 1993
OEL-POLAND:TWA 0.3 mg(Mn)/m3 JANUARY 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m
3;STEL 2.5 mg(Mn)/m3 (resp. dust) OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5
mg(Mn)/m3 (total dust) OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JANUARY 1
993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN
NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.