Material Safety Data
Manganese (II) Sulfate Monohydrate
Section 1 - Chemical Product and Company
MSDS Name: Manganese (II) Sulfate
Catalog Numbers: S80061ACS, S80071-2, M113 3,
M113 500, M113-3, M113-500, M1133, M113500, M114-12, M114-212, M114-500,
M114212, M114500, M11512, M115212, M115500, NC9747671
Manganese(II) sulfate, monohydrate, manganous sulfate monohydrate
Fair Lawn, NJ 07410
For information, call: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
International CHEMTREC assistance, call: 703-527-3887
Section 2 -
Composition, Information on Ingredients
||Manganese sulfate, monohydrate
Hazard Symbols: XN
Section 3 - Hazards
Appearance: pink. Caution! May cause eye and skin
irritation. May cause respiratory and digestive tract irritation. May cause
central nervous system effects. Hygroscopic.
Central nervous system.
Eye: May cause mild eye irritation.
Skin: May cause skin irritation. Low hazard for usual
Ingestion: May cause gastrointestinal
irritation with nausea, vomiting and diarrhea.
May cause respiratory tract irritation.
inhalation or ingestion may cause argyria characterized by blue-gray
discoloration of the eyes, skin and mucous membrances. Chronic skin contact may
cause permanent discoloration of the skin.
Section 4 - First Aid
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of soap and water for at least
15 minutes while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Remove contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an unconscious person.
Get medical aid.
Inhalation: Remove from exposure to fresh
air immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen.
Notes to Physician: Treat
symptomatically and supportively.
Antidote: The use of
Calcium disodium EDTA as a chelating agent should be determined by qualified
Section 5 - Fire
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Material will not burn.
Extinguishing Media: For
small fires, use water spray, dry chemical, carbon dioxide or chemical foam.
Section 6 -
Accidental Release Measures
Information: Use proper personal protective equipment as indicated in
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Avoid generating dusty conditions.
Section 7 - Handling
Handling: Wash hands before eating. Use with
adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and
Storage: Store in a tightly closed container.
Section 8 - Exposure
Controls, Personal Protection
Controls: Use adequate general or local exhaust ventilation to keep
airborne concentrations below the permissible exposure limits.
|Manganese sulfate, monohydrate
OSHA Vacated PELs:
Manganese sulfate, monohydrate: No OSHA Vacated PELs are listed for this
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face protection regulations in 29
CFR 1910.133 or European Standard EN166.
Clothing: Wear appropriate protective
gloves and clothing to prevent skin exposure.
Respirators: Follow the
OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149 approved respirator when
Section 9 - Physical
and Chemical Properties
Vapor Pressure: Not available.
Evaporation Rate:Not available.
Boiling Point: 1562 deg F
Point:1292 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0;
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Completely soluble in
Specific Gravity/Density:3.25 (water=1)
Section 10 -
Stability and Reactivity
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Can react with strong acid,
strong oxidizing agents, powdered metals; may react violently with hydrogen
Hazardous Decomposition Products: Carbon dioxide, sulfur
oxides (SOx), including sulfur oxide and sulfur dioxide, oxides of manganese.
Hazardous Polymerization: Has not been reported.
Section 11 -
CAS# 10034-96-5: OP0893500
CAS# 10034-96-5: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
Section 12 -
No information available.
Section 13 - Disposal
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 -
||No information available.
||No information available.|
Section 15 -
CAS# 10034-96-5 is not on the TSCA
Inventory. It is a hydrate and exempt from TSCA Inventory requirements
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
None of the chemicals in this product are under a Chemical Test
None of the chemicals are listed under TSCA
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
None of the chemicals in this material have an RQ.
None of the chemicals in this product have a TPQ.
CAS # 10034-96-5: chronic.
contains Manganese sulfate, monohydrate (listed as ** undefined **), 98%, (CAS#
10034-96-5) which is subject to the reporting requirements of Section 313 of
SARA Title III and 40 CFR Part 373.
Clean Air Act:
does not contain any hazardous air pollutants. This material does not contain
any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA. None of the chemicals in this
product are listed as Priority Pollutants under the CWA. None of the chemicals
in this product are listed as Toxic Pollutants under the CWA.
None of the chemicals in this product are considered highly
hazardous by OSHA.
CAS# 10034-96-5 is not present on state
lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed. European/International
European Labeling in Accordance with EC
40/20/22 Harmful : possible risk of irreversible
effects through inhalation
and if swallowed.
CAS# 10034-96-5: 1
None of the chemicals in this product
are listed on the DSL or NDSL list. This product has a WHMIS classification of
CAS# 10034-96-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10034-96-5: OEL-AUSTRALIA:TWA 5 mg(Mn)/m3
JANUARY 1993 OEL-BE
LGIUM:TWA 5 mg(Mn)/m3 JANUARY 1993 OEL-CZECHOSLOVAKIA:TWA
3;STEL 6 mg(Mn)/m3 JANUARY 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3
RY 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JANUARY 1993 OEL-HUNGARY:TWA
0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JANUARY 1993 OEL-JAPAN:TWA 0.3
)/m3 JANUARY 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JANUARY 1993
OEL-POLAND:TWA 0.3 mg(Mn)/m3 JANUARY 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m
3;STEL 2.5 mg(Mn)/m3 (resp. dust) OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL
mg(Mn)/m3 (total dust) OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JANUARY 1
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN
SINGAPORE, VIETNAM check ACGI TLV
Section 16 -
MSDS Creation Date:
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.