Material Safety Data
Sheet
Magnesium Oxide
ACC# 13450
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Magnesium Oxide
Catalog Numbers: S80066, M300 500, M300-500, M300500, M3494
500, M3494-500, M3494500, M51 100, M51 500, M51-100, M51-500, M51100, M51500,
M68 3, M68-3, M683, NC9534192, XXM6850KG
Synonyms: Magnesia, Calcined
Magnesium, Calcined Brucite
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 1309-48-4 |
Magnesium oxide |
100 |
215-171-9 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Caution! May cause eye and skin
irritation. Inhalation of fumes may cause metal-fume fever. May cause
respiratory tract irritation.
Target Organs: Respiratory
system, eyes, mucous membranes.
Potential Health
Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: Causes gastrointestinal irritation with nausea,
vomiting and diarrhea.
Inhalation: May cause respiratory
tract irritation. Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever, chills, cough,
weakness, chest pain, muscle pain and increased white blood cell count.
Chronic: No information found.
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Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Get medical aid if irritation develops
or persists. Rinse area with large amounts of water for at least 15 minutes.
Remove contaminated clothing and shoes.
Ingestion: If
victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical
aid.
Inhalation: Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid.
Notes to
Physician: Treat symptomatically and supportively.
Antidote: The use of Calcium gluconate to precipitate the
oxalate should be determined by only qualified medical personnel.
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Section 5 - Fire
Fighting Measures |
General
Information: Substance is noncombustible.
Extinguishing
Media: Use extinguishing media most appropriate for the surrounding
fire.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Sweep up, then place into a
suitable container for disposal. Avoid generating dusty conditions.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Minimize
dust generation and accumulation. Avoid contact with skin and eyes. Avoid
ingestion and inhalation. Use with adequate ventilation.
Storage: Store in a cool, dry place.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Good general ventilation should be sufficient to control
airborne levels.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Magnesium oxide |
10 mg/m3 TWA |
no established RELs - see Appendix D 750
mg/m3 IDLH |
total particulate: 15 mg/m3
TWA |
OSHA Vacated PELs: Magnesium
oxide: total particulate: 10 mg/m3 TWA
Personal Protective
Equipment
Eyes: Wear chemical goggles.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to
prevent skin exposure.
Respirators: Follow the OSHA respirator
regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: odorless
pH: Not
available.
Vapor Pressure: Not available.
Vapor Density:
Not available.
Evaporation Rate:Not available.
Viscosity:
Not available.
Boiling Point: 3582 deg C
Freezing/Melting
Point:2800 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:Not
available.
NFPA Rating: (estimated) Health: 1; Flammability: 0;
Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Slightly soluble in
water
Specific Gravity/Density:3.58
Molecular Formula:MgO
Molecular Weight:40.3044
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Incompatible
materials.
Incompatibilities with Other Materials: Reacts violently
with interhalogens such as chlorine trifluoride (ClF3) or bromine pentafluoride
(BrF3). Reacts incandescantly with phosphorus pentachloride (PCl5). Reacts
exothermically with water to form magnesium hydroxide.
Hazardous
Decomposition Products: None.
Hazardous Polymerization: Will not
occur.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 1309-48-4: OM3850000
LD50/LC50:
Not
available.
Carcinogenicity:
CAS# 1309-48-4: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects:
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
available.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 1309-48-4 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 1309-48-4 can be found on the following state right to
know lists: California, New Jersey, Florida, Pennsylvania, Minnesota,
Massachusetts.
California No Significant Risk Level: None of the chemicals
in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 1309-48-4: 1
Canada
CAS# 1309-48-4
is listed on Canada's DSL List. CAS# 1309-48-4 is listed on Canada's DSL List.
This product has a WHMIS classification of Not controlled..
CAS#
1309-48-4 is listed on Canada's Ingredient Disclosure List.
Exposure
Limits
CAS# 1309-48-4: OEL-ARAB Republic of Egypt:TWA 10 mg/m3
OEL-AUSTRAL
IA:TWA 10 mg/m3 JANUARY 1993 OEL-BELGIUM:TWA 10 mg/m3 JANUARY
1993
OEL-DENMARK:TWA 6 mg/m3 OEL-FRANCE:TWA 10 mg/m3 JANUARY 1993 OEL-G
ERMANY:TWA 6 mg/m3 OEL-GERMANY:TWA 6 mg/m3 JANUARY 1993 OEL-HUNGARY
:TWA
5 mg/m3;STEL 10 mg/m3 OEL-THE NETHERLANDS:TWA 10 mg/m3 JANUARY
1993 OEL-THE
PHILIPPINES:TWA 15 mg/m3 JANUARY 1993 OEL-POLAND:TWA 1
5 mg/m3
OEL-RUSSIA:STEL 5 mg/m3 OEL-SWITZERLAND:TWA 6 mg/m3 OEL-SWI
TZERLAND:TWA 6
mg/m3;STEL 12 mg/m3 JANUAR 1993 OEL-TURKEY:TWA 15 mg/
m3 OEL-UNITED
KINGDOM:TWA 10 mg/m3 JANUARY 1993 OEL-UNITED KINGDOM:
TWA 10 mg/m3 (total
dust) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA c
heck ACGIH TLV OEL IN NEW
ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
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Section 16 -
Additional Information |
MSDS Creation Date:
12/12/1997
Revision #3 Date: 8/02/2001
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.