Material Safety Data
Sheet
Magnesium Chloride Hexahydrate
ACC# 13365
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Magnesium Chloride
Hexahydrate
Catalog Numbers: S80063, S80063-1, BP214 500,
BP214-500, BP214500, BP2638, CRNM33500, M33 3, M33 500, M33-10, M33-100, M33-3,
M33-500, M3310, M33100, M333, M33500, M35, M35-12, M35-212, M35-500, M35212,
M35500, M3612, M36212, NC9523446, S800631, S800632, S99098
Synonyms:
Dus-Top; Mangogene.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7791-18-6 |
Magnesium Chloride Hexahydrate |
100 |
unlisted
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Hazard Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white to gray white. Causes eye and skin irritation. Causes
digestive and respiratory tract irritation. May cause kidney damage. Inhalation
of fumes may cause metal-fume fever. Warning!
Target Organs: Kidneys.
Potential Health
Effects
Eye: May cause mild eye irritation.
Skin: May cause skin irritation.
Ingestion: Causes gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause kidney damage.
Inhalation:
May cause respiratory tract irritation. Inhalation of fumes may cause metal fume
fever, which is characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white blood cell
count.
Chronic: May cause kidney damage.
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Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated clothing and
shoes. Get medical aid if irritation develops or persists. Wash clothing before
reuse.
Ingestion: Do NOT induce vomiting. If victim is
conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Inhalation: Get medical aid immediately. Remove from
exposure to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician: Treat symptomatically
and supportively.
Antidote: The use of Calcium gluconate to
precipitate the oxalate should be determined by only qualified medical
personnel.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Material will not burn. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water with caution
and in flooding amounts.
Extinguishing Media: Use
extinguishing media most appropriate for the surrounding fire.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up or absorb
material, then place into a suitable clean, dry, closed container for disposal.
Avoid generating dusty conditions. Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash hands before eating. Use with
adequate ventilation. Minimize dust generation and accumulation. Avoid contact
with eyes, skin, and clothing.
Storage: Store in a cool,
dry, well-ventilated area away from incompatible substances. Keep away from
water.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Good general ventilation should be sufficient to control
airborne levels. Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower.
Exposure
Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Magnesium Chloride Hexahydrate |
none listed |
none listed |
none
listed |
OSHA Vacated PELs:
Magnesium Chloride Hexahydrate: No OSHA Vacated PELs are listed for this
chemical.
Personal Protective Equipment
Eyes: Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent
skin exposure.
Respirators: Follow the OSHA respirator regulations
found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or
European Standard EN 149 approved respirator when necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white to gray white
Odor: none reported
pH: 7.0 (Solution)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not
available.
Viscosity: Not available.
Boiling Point: 1412
deg C
Freezing/Melting Point:118 deg C
Autoignition
Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:100 deg C
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Reactivity: 0
Explosion Limits,
Lower:Not available.
Upper: Not available.
Solubility:
Soluble in water and alcohol
Specific Gravity/Density:1.569
Molecular Formula:MgCl2.6H2O
Molecular Weight:203.2914
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Heating to decomposition.
Incompatibilities with Other
Materials: Explosive when combined with 2-furan percarboxylic acid.
Magnesium chloride dissolves in aqueous solutions giving off considerable
ammounts of heat; Incompatible with strong oxidizers
Hazardous
Decomposition Products: Hydrogen chloride, chlorine.
Hazardous
Polymerization: Will not occur.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 7791-18-6: OM2975000
LD50/LC50:
CAS#
7791-18-6:
Oral, mouse: LD50 = 7600 mg/kg;
Oral, rat: LD50 = 8100
mg/kg;
Carcinogenicity:
CAS# 7791-18-6: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information found.
Teratogenicity: No information found.
Reproductive
Effects: No information found.
Neurotoxicity: No information
found.
Mutagenicity: No information found.
Other Studies:
See actual entry in RTECS for complete information.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7791-18-6 is not on the TSCA
Inventory. It is a hydrate and exempt from TSCA Inventory requirements
(40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants. This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this product are listed as
Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the
chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7791-18-6 is not present on state lists from CA, PA,
MN, MA, FL, or NJ.
California No Significant Risk Level: None of the
chemicals in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 7791-18-6: 0
Canada
Canada
None of the chemicals in this product
are listed on the DSL or NDSL list. This product has a WHMIS classification of
D2B.
CAS# 7791-18-6 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
9/02/1997
Revision #4 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.