Material Safety Data Sheet
Potassium hydroxide solutions, 10% - 55% W/V, 0.1N - 1.0N

ACC# 75112
Section 1 - Chemical Product and Company Identification

MSDS Name: Potassium hydroxide solutions, 10% - 55% W/V, 0.1N - 1.0N
Catalog Numbers: LC19200, LC19220, LC19240, LC19250, LC19260, LC19270, LC19300, LC19320, LC19350
Synonyms:

Company Identification:

              Labchem Inc.
              200 William Pitt Way
              Pittsburgh, PA 15238
For information, call:
412-826-5230
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
1310-58-3 Potassium hydroxide 1-55 215-181-3
7732-18-5 Water balance 231-791-2

Hazard Symbols:
C
Risk Phrases:
35

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless. Danger! Corrosive. Causes eye and skin burns. Causes digestive and respiratory tract burns.
Target Organs: None.


Potential Health Effects
Eye: Causes severe eye burns. May cause irreversible eye injury. Contact may cause ulceration of the conjunctiva and cornea. Eye damage may be delayed. Causes redness, pain, and irritation.
Skin: May cause deep, penetrating ulcers of the skin. Causes severe burns with delayed tissue destruction.
Ingestion: May cause circulatory system failure. May cause perforation of the digestive tract. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death.
Inhalation: Irritation may lead to chemical pneumonitis and pulmonary edema. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. Palpitation, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema may result from inhalation exposure.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact may cause conjunctivitis.

Section 4 - First Aid Measures


Eyes: Get medical aid at once. Immediately flush eyes with water lifting upper/lower lids occasionally until chemical is gone (15-20min.)
Skin: Get medical aid at once. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing to reduce further exposure. Cover burns with a dry sterile bandage (loose, not tight).
Ingestion: Do NOT induce vomiting. Give conscious victim 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid at once. Medical personnel may do esophagoscopy, irrigate injured area with 1% acetic acid to neutralize alkali.
Inhalation: Get medical aid at once. Move victim to fresh air immediately. Give artificial respiration if necessary. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Firefighting Measures


General Information: Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Use water with caution and in flooding amounts. Contact with moisture or water may generate sufficient heat to ignite nearby combustible materials.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. DO NOT USE WATER!

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Do not allow water to get into the container because of violent reaction. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage: Store in a cool, dry area. Store in a tightly closed container. Keep away from strong acids. Keep away from water. Keep away from metals.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Potassium hydroxide C 2 mg/m3 2 mg/m3 TWA none listed
Water none listed none listed none listed

OSHA Vacated PELs: Potassium hydroxide: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: > 212 deg F
Freezing/Melting Point:< 32 deg F
Decomposition Temperature:Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: soluble
Specific Gravity/Density:>1
Molecular Formula:KOH
Molecular Weight:56.10

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Acids - organic materials - acrolein - nitro compounds - halogens - acid anhydrides - phosphorus - potassium - metals.
Hazardous Decomposition Products: Hydrogen gas, oxides of potassium.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:
CAS# 1310-58-3 unlisted.
CAS# 7732-18-5 unlisted.
LD50/LC50:
CAS# 1310-58-3:
Oral, rat: LD50 = 273 mg/kg;
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 1310-58-3: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

Section 12 - Ecological Information


Ecotoxicity: No data available. cfr. DOSE
Environmental: No information available.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT IATA RID/ADR IMO Canada TDG
Shipping Name: POTASSIUM HYDROXIDE SOLUTION No information available.
Hazard Class: 8
UN Number: UN1814
Packing Group: PG II

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 1310-58-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
CAS# 1310-58-3: final RQ = 1000 pounds (454 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1310-58-3: acute, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-58-3 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 1310-58-3 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:

R 35 Causes severe burns.

Safety Phrases:

S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident of if you feel unwell, seek
medical advice immediately (show the label where
possible).

WGK (Water Danger/Protection)

CAS# 1310-58-3: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 1310-58-3 is listed on Canada's DSL List. CAS# 1310-58-3 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.

WHMIS: Not available.
CAS# 1310-58-3 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 1310-58-3: OEL-AUSTRALIA:TWA 2 mg/m3 OEL-BELGIUM:STEL 2 mg/m3
OEL-DENMARK:TWA 2 mg/m3 OEL-FINLAND:TWA 2 mg/m3 OEL-FRANCE:STEL 2 m
g/m3 OEL-JAPAN:STEL 2 mg/m3 OEL-THE NETHERLANDS:TWA 2 mg/m3 OEL-SWI
TZERLAND:TWA 2 mg/m3 OEL-UNITED KINGDOM:TWA 2 mg/m3;STEL 2 mg/m3 OEL
IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEAL
AND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 11/09/1998
Revision #1 Date: 12/06/2000
Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application.