Material Safety Data
Sheet
Potassium Nitrate
ACC# 19470
|
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Potassium Nitrate
Catalog Numbers: AC424150030, S77585, S77588, S77588-2,
BP368-500, NC9613818, P261-3, P263-100, P263-3, P263-50, P263-500, P26350KG,
P383-100, P383-500, S73066, XXP263295LB
Synonyms: Nitric Acid
Potassium Salt, Niter, Saltpeter
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC
assistance, call: 800-424-9300
For International CHEMTREC assistance,
call: 703-527-3887
|
Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7757-79-1 |
Nitric acid potassium salt |
100 |
231-818-8 |
Hazard
Symbols: O
Risk Phrases: 8
|
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Danger! Strong oxidizer. Contact with
other material may cause a fire. May cause respiratory tract irritation. May
cause eye and skin irritation. May cause digestive tract irritation with nausea,
vomiting, and diarrhea. May cause methemoglobinemia. May cause kidney damage.
May cause blood abnormalities.
Target Organs: Blood,
kidneys.
Potential Health Effects
Eye: May cause eye irritation.
Skin: Dust causes mechanical irritation. Low hazard for
usual industrial handling.
Ingestion: Causes
gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause respiratory tract irritation. May
cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea (labored
breathing), and death.
Chronic: Prolonged exposure may
cause anemia and methemoglobinemia, characterized by dizziness, drowsiness,
headache, breath shortness, cyanosis (bluish skin due to deficient oxygenation
of the blood), rapid heart rate and chocolate-brown colored blood. May cause
kidney injury. May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath shortness,
cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate,
unconsciousness and possible death.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of soap and water for at least
15 minutes while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious
and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation: Remove
from exposure to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
|
Section 5 - Fire
Fighting Measures |
General
Information: Strong oxidizer. Contact with combustible materials may
cause a fire. During a fire, irritating and highly toxic gases may be generated
by thermal decomposition or combustion. Wear appropriate protective clothing to
prevent contact with skin and eyes. Wear a self-contained breathing apparatus
(SCBA) to prevent contact with thermal decomposition products. Containers may
explode in the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. May decompose explosively
when heated or involved in a fire. May accelerate burning if involved in a fire.
May explode from heat or contamination.
Extinguishing
Media: Cool containers with flooding quantities of water until well
after fire is out. For small fires, do NOT use dry chemicals, carbon dioxide,
halon or foams. USE WATER ONLY. For large fires flood fire with water from a
distance.
|
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Remove all sources of ignition. Provide ventilation. Do not use
combustible materials such as paper towels to clean up spill.
|
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Avoid
prolonged or repeated contact with skin. Avoid contact with eyes. Keep container
tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Wash clothing before reuse. Keep away from clothing and other combustible
materials.
Storage: Do not store near combustible
materials. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away from reducing
agents.
|
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Nitric acid potassium salt |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Nitric
acid potassium salt: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate gloves to prevent
skin exposure.
Clothing: Wear appropriate protective
clothing to prevent skin exposure.
Respirators: Follow the OSHA
respirator regulations found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
|
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: odorless
pH:
4.5-7.0: 5% solution
Vapor Pressure: Not available.
Vapor
Density: 3.5
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:334 deg C
Autoignition Temperature:
Not available.
Flash Point: Not available.
Decomposition
Temperature:400 deg C
NFPA Rating: (estimated) Health: 2;
Flammability: 0; Reactivity: 1
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: soluble in water
Specific Gravity/Density:2.1
Molecular Formula:KNO3
Molecular Weight:101.1032
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: Incompatible materials, dust generation, combustible materials,
reducing agents.
Incompatibilities with Other Materials: Reacts
violently with organic materials, combustible materials, and reducing agents.
Specific incompatibles under various conditions include aluminum, titanium,
antimony, germanium, zinc, zirconium, calcium disilicide, chromium nitride,
metal sulfides, boron, carbon, sulfur, phosphorus, phosphides, sodium
phosphinate, sodium thiosulfate, citric acid, tin chloride, sodium acetate, and
thorium carbide.
Hazardous Decomposition Products: Nitrogen oxides,
irritating and toxic fumes and gases, oxygen.
Hazardous
Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 7757-79-1: TT3700000
LD50/LC50:
CAS#
7757-79-1:
Oral, rabbit: LD50 = 1901 mg/kg;
Oral, rat: LD50 = 3750
mg/kg;
Carcinogenicity:
CAS# 7757-79-1: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information
available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No
information available.
Other Studies: No data available.
|
Section 12 -
Ecological Information |
No information available.
|
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
|
US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
POTASSIUM NITRATE |
|
|
|
POTASSIUM NITRATE |
| Hazard Class: |
5.1 |
|
|
|
5.1 |
| UN Number: |
UN1486 |
|
|
|
UN1486 |
| Packing Group: |
III |
|
|
|
III |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7757-79-1 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 7757-79-1: acute, chronic, flammable.
Section
313
No chemicals are reportable under Section 313.
Clean Air
Act:
This material does not contain any hazardous air pollutants. This
material does not contain any Class 1 Ozone depletors. This material does not
contain any Class 2 Ozone depletors.
Clean Water Act:
None of the
chemicals in this product are listed as Hazardous Substances under the CWA. None
of the chemicals in this product are listed as Priority Pollutants under the
CWA. None of the chemicals in this product are listed as Toxic Pollutants under
the CWA.
OSHA:
None of the chemicals in this product are
considered highly hazardous by OSHA.
STATE
CAS# 7757-79-1 can be
found on the following state right to know lists: New Jersey, Florida,
Pennsylvania, Massachusetts.
California No Significant Risk Level: None of
the chemicals in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
O
Risk Phrases:
R 8
Contact with combustible material may cause
fire.
Safety
Phrases:
WGK (Water Danger/Protection)
CAS# 7757-79-1: 1
Canada
CAS# 7757-79-1 is listed on Canada's DSL List. CAS#
7757-79-1 is listed on Canada's DSL List.
This product has a WHMIS
classification of C, D2A.
CAS# 7757-79-1 is not listed on Canada's
Ingredient Disclosure List.
Exposure Limits
CAS# 7757-79-1:
OEL-THE NETHERLANDS:TWA 2 ppm (5 mg/m3) OEL-RUSSIA:
STEL 5 mg/m3
|
Section 16 -
Additional Information |
MSDS Creation Date:
8/14/1998
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.