Material Safety Data
Sheet
Potassium Carbonate Anhydrous
ACC# 19290
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Potassium Carbonate
Anhydrous
Catalog Numbers: S80135, BP365-500, NC9680948,
P208-3, P208-500, P208250LB
Synonyms: Dipotassium salt of carbonic
acid; Pearl ash; Potash.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 584-08-7 |
Carbonic acid, dipotassium salt |
>99.0 |
209-529-3 |
Hazard
Symbols: XN
Risk Phrases: 22 36/37/38
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Warning! May be harmful if swallowed.
Causes eye and skin irritation and possible burns. Causes respiratory tract
irritation. Hygroscopic.
Target Organs: Eyes, skin, mucous
membranes.
Potential Health Effects
Eye: Causes eye irritation. Causes an irritant and
caustic action similar to that of potassium hydroxide.
Skin: Causes an irritant and caustic action similar to that
of potassium hydroxide.
Ingestion: May cause severe
gastrointestinal tract irritation with nausea, vomiting and possible burns. May
be harmful if swallowed.
Inhalation: Causes respiratory
tract irritation.
Chronic: No information found.
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Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid immediately.
Skin: Get medical aid. Immediately
flush skin with plenty of soap and water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious
and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid if cough or other symptoms appear.
Notes to
Physician: Treat symptomatically and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up, then place
into a suitable container for disposal. Avoid generating dusty conditions.
Provide ventilation.
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Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Minimize
dust generation and accumulation. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation. Use with adequate ventilation.
Storage: Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Carbonic acid, dipotassium salt |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Carbonic
acid, dipotassium salt: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear appropriate
protective clothing to prevent skin exposure.
Respirators: Follow the
OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: odorless
pH: 11.6
in soln
Vapor Pressure: Not available.
Vapor Density: Not
available.
Evaporation Rate:Not available.
Viscosity: Not
available.
Boiling Point: Not available.
Freezing/Melting
Point:891 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not
available.
NFPA Rating: (estimated) Health: 2; Flammability: 0;
Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble in water
Specific Gravity/Density:(H2O=1) 2.29
Molecular
Formula:K2CO3
Molecular Weight:138.21
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable.
Conditions to Avoid: Dust generation, excess
heat, exposure to moist air or water.
Incompatibilities with Other
Materials: Acids, metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of potassium.
Hazardous
Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 584-08-7: TS7750000
LD50/LC50:
CAS#
584-08-7:
Oral, mouse: LD50 = 2570 mg/kg;
Oral, rat: LD50 = 1870
mg/kg;
Carcinogenicity:
CAS# 584-08-7: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information
present.
Teratogenicity: No information present.
Reproductive
Effects: No information present.
Neurotoxicity: No information
present.
Mutagenicity: No information present.
Other
Studies: See actual entry in RTECS for complete information.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 584-08-7 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 584-08-7: acute.
Section 313
No chemicals are
reportable under Section 313.
Clean Air Act:
This material does
not contain any hazardous air pollutants. This material does not contain any
Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA. None of the chemicals in this
product are listed as Priority Pollutants under the CWA. None of the chemicals
in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly
hazardous by OSHA.
STATE
CAS# 584-08-7 is not present on state
lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level:
None of the chemicals in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
XN
Risk Phrases:
R 22
Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with
eyes, rinse immediately
with plenty of water and seek medical advice.
S
37/39 Wear suitable gloves and eye/face
protection.
WGK (Water
Danger/Protection)
CAS# 584-08-7: 1
Canada
CAS# 584-08-7 is
listed on Canada's DSL List. CAS# 584-08-7 is listed on Canada's DSL List.
This product has a WHMIS classification of D2B.
CAS# 584-08-7 is listed
on Canada's Ingredient Disclosure List.
Exposure Limits
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Section 16 -
Additional Information |
MSDS Creation Date:
4/27/1999
Revision #4 Date: 8/03/2001
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.