Material Safety Data
Sheet
Iron
ACC# 11490
|
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Iron
Catalog
Numbers: S71953, S71953-1, I60 3, I60 500, I60-3, I60-500, I603,
I60500, I62 500, I62-500, I62500, S71953-2, S719531, S719532
Synonyms: Iron Dust; Iron Metal; Iron Powder.
Company
Identification:
Fisher
Scientific
1 Reagent
Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For
International CHEMTREC assistance, call: 703-527-3887
|
Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7439-89-6 |
IRON |
>97 |
231-096-4 |
Hazard
Symbols: None listed.
Risk Phrases: None listed.
|
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: black to gray. Warning! Flammable solid. May
cause blood abnormalities. Inhalation of fumes may cause metal-fume fever. May
cause lung damage. May cause cardiac disturbances. May cause liver damage. May
cause mechanical eye and skin irritation.
Target Organs:
Liver, respiratory system, cardiovascular system, pancreas.
Potential Health Effects
Eye: Exposure to particulates or solution may cause
conjunctivitis, ulceration, and corneal abnormalities.
Skin: May cause skin irritation.
Ingestion: May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. Acute toxicity may include weakness, shock,
cyanosis and acidosis. Delayed symptoms may include liver damage.
Inhalation: Inhalation of fumes may cause metal fume fever,
which is characterized by flu-like symptoms with metallic taste, fever, chills,
cough, weakness, chest pain, muscle pain and increased white blood cell count.
May cause lung damage.
Chronic: Chronic exposure may lead
to liver and lung damage. Repeated exposure may cause pancreatic damage,
diabetes, and cardiac abnormalities.
|
Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid immediately.
Skin: Immediately flush skin with
plenty of soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid if cough or other symptoms appear.
Notes to
Physician: Treat symptomatically and supportively.
Antidote: The use of Deferoxamine as a chelating agent
should be determined only by qualified medical personnel.
|
Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Dusts at sufficient concentrations can form explosive mixtures with air.
Combustion generates toxic fumes.
Extinguishing Media: Use
only graphite powder, soda ash, powdered sodium chloride, or an appropriate
metal-fire-extinguishing dry powder.
|
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Sweep up or absorb material, then
place into a suitable clean, dry, closed container for disposal. Avoid
generating dusty conditions. Remove all sources of ignition.
|
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Remove
contaminated clothing and wash before reuse. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Keep from contact with oxidizing materials. Store
in a cool, dry, well-ventilated area away from incompatible substances.
|
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure
Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| IRON |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: IRON: No
OSHA Vacated PELs are listed for this chemical.
Personal Protective
Equipment
Eyes: Wear appropriate protective
eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear impervious gloves.
Clothing: Wear appropriate protective clothing to prevent
skin exposure.
Respirators: Follow the OSHA respirator regulations
found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or
European Standard EN 149 approved respirator when necessary.
|
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: black to gray
Odor: none reported
pH: Not available.
Vapor Pressure: 1 mm Hg @ 1787C
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 4982 deg F
Freezing/Melting Point:2795 deg F
Autoignition
Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating:
Explosion Limits, Lower:Not available.
Upper: Not
available.
Solubility: Insoluble in water.
Specific
Gravity/Density:7.86 @ 20C
Molecular Formula:Fe
Molecular
Weight:55.847
|
Section 10 -
Stability and Reactivity |
Chemical
Stability: Decomposes when heated. Oxidizes when exposed to air.
Conditions to Avoid: Incompatible materials, moisture, exposure to
air, excess heat.
Incompatibilities with Other Materials:
Acetaldehyde, ammonium peroxodisulfate, chloroformamidinium, chloric acid,
ammonium nitrate, halogens, dinitrogen tetroxide, nitryl fluoride, polystyrene,
sodium acetylide, potassium dichromate, peroxyformic acid, nitryl fluoride,
sulfuric acid, sodium carbide.
Hazardous Decomposition Products:
Oxides of iron.
Hazardous Polymerization: Has not been reported.
|
Section 11 -
Toxicological Information |
RTECS#:
CAS# 7439-89-6: NO4565500
LD50/LC50:
CAS#
7439-89-6:
Oral, rat: LD50 = 30 gm/kg;
Carcinogenicity:
CAS# 7439-89-6: Not listed by ACGIH, IARC, NIOSH,
NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Neurotoxicity: No information
available.
Mutagenicity: No information available.
Other
Studies: None.
|
Section 12 -
Ecological Information |
Ecotoxicity: No
data available. No information available.
Environmental: No
information reported.
Physical: No information available.
Other: None.
|
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 -
Transport Information |
|
US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
METAL POWDER, FLAMMABLE, N.O.S. (IRON) |
|
|
|
METAL POWDERS FLAMMABLE NOS (IRON) |
| Hazard Class: |
4.1 |
|
|
|
4.1 |
| UN Number: |
UN3089 |
|
|
|
UN3089 |
| Packing Group: |
II |
|
|
|
III |
|
Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7439-89-6 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 7439-89-6: acute, flammable.
Section 313
No
chemicals are reportable under Section 313.
Clean Air Act:
This
material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2
Ozone depletors.
Clean Water Act:
None of the chemicals in this
product are listed as Hazardous Substances under the CWA. None of the chemicals
in this product are listed as Priority Pollutants under the CWA. None of the
chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly
hazardous by OSHA.
STATE
CAS# 7439-89-6 can be found on the
following state right to know lists: California.
California No Significant
Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in
Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 7439-89-6: 0
Canada
CAS# 7439-89-6
is listed on Canada's DSL List. CAS# 7439-89-6 is listed on Canada's DSL List.
This product has a WHMIS classification of B4, D2B.
CAS# 7439-89-6 is
not listed on Canada's Ingredient Disclosure List.
Exposure
Limits
|
Section 16 -
Additional Information |
MSDS Creation Date:
12/12/1997
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.