MSDS Name: Copper (cupric) sulfate solutions
Catalog Numbers: LC13410, LC13420, LC13440, LC14200
Synonyms: copper (II) sulfate solutions; specific gravity solutions
Company Identification:
              Labchem Inc.
              200 William Pitt Way
              Pittsburgh, PA 15238
For information, call: 412-826-5230
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid at once.
Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion: Give conscious non-convulsive victim large quantities of water or milk and remove by gastric lavage unless victim is already vomiting.
Inhalation: Give artificial respiration if necessary. Get medical aid. Keep victim warm, at rest. Move victim to fresh air.
Notes to Physician: Treat symptomatically.
Antidote: Medical personnel give calcium disodium EDTA orally or intravenously. Penicillamine is also effective in treating copper poisoning. (Driesbach, Handbook of Poisoning, 11th Ed.)

Section 5 - Firefighting Measures

General Information: Negligible fire and explosion hazard when exposed to heat or flame. Move container if possible, avoid breathing vapors or dust.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal. Material may be neutralized to pH 7 with citric acid or other suitable neutralizing agent.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Avoid breathing dust, vapor, mist, or gas.
Storage: Store capped at room temperature. Protect from heat and incompatibles.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Provide local exhaust or general dilution ventilation.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Cupric sulfate anhydrous OR.......	none listed	none listed	none listed
Cupric sulfate pentahydrate	none listed	none listed	none listed
Water	none listed	none listed	none listed

OSHA Vacated PELs: Cupric sulfate anhydrous OR.......: No OSHA Vacated PELs are listed for this chemical. Cupric sulfate pentahydrate: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Do not wear contact lenses when working with chemicals. An eye wash fountain should be available in the immediate work area. Wear splash-proof safety goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Firefighting-- any self-contained breathing apparatus with full facepiece operated in pressure-demand mode. 50mg/M3 HiEPF/SAF/SCBAF. /M3 SAF:PD,PP,CF. ighting- SCBAF:PD.PP.

Section 9 - Physical and Chemical Properties

Physical State: Clear liquid
Appearance: blue
Odor: odorless
pH: 3-5
Vapor Pressure: 14mm Hg @20 deg C
Vapor Density: 0.7 (H2O)
Evaporation Rate:< ether
Viscosity: Not available.
Boiling Point: > 212 deg F
Freezing/Melting Point:< 32 deg F
Decomposition Temperature:Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble.
Specific Gravity/Density:1.0
Molecular Formula:Not available.
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Hydroxylamine, magnesium, acetylene.
Hazardous Decomposition Products: Not available.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information

RTECS#:
CAS# 7558-98-7 unlisted.
CAS# 7558-99-8 unlisted.
CAS# 7732-18-5 unlisted.
LD50/LC50:
Not available.
Not available.

CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 7558-98-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7558-99-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: copper sulfate solutions may irritate eyes, skin, respirator y, and mucous membranes. Poisoning may affect the centra l nervous system, liver, kidneys, and capillaries.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	No information available.				No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7558-98-7 is not listed on the TSCA inventory. It is for research and development use only.
CAS# 7558-99-8 is not listed on the TSCA inventory. It is for research and development use only.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7558-98-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7558-99-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:

Safety Phrases:

WGK (Water Danger/Protection)
CAS# 7558-98-7: No information available.
CAS# 7558-99-8: No information available.
CAS# 7732-18-5: No information available.
Canada
Canada
Canada
CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.


WHMIS: Not available.
CAS# 7558-98-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7558-99-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits

Section 16 - Additional Information

MSDS Creation Date: 2/16/1998
Revision #3 Date: 1/01/2001
Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application.