Material Safety Data
Sheet
Copper(i) iodide, 98%
ACC# 35167
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Copper(i) iodide, 98%
Catalog Numbers:
AC194900000, AC194900010, AC194902500
Synonyms: None.
Company
Identification:
Acros
Organics N.V.
One Reagent
Lane
Fair Lawn, NJ
07410
For information in North America, call: 800-ACROS-01
For
emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7681-65-4 |
Copper(I) iodide |
98.0 |
231-674-6 |
Hazard
Symbols: XI
Risk Phrases: 36/37/38
|
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white to gray-beige. Caution! Causes eye and
skin irritation. The toxicological properties of this material have not been
fully investigated. Light sensitive. Harmful if swallowed. Causes respiratory
tract irritation. May cause digestive tract irritation.
Target
Organs: None.
Potential Health
Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: May cause irritation of the digestive tract. The
toxicological properties of this substance have not been fully investigated. May
be harmful if swallowed.
Inhalation: Dust is irritating to
the respiratory tract.
Chronic: No information found.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin: Get medical aid. Flush skin with plenty
of soap and water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion: If victim is conscious and alert,
give 2-4 cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid.
Notes to Physician: Treat
symptomatically and supportively.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Substance is noncombustible. May form very
sensitive, explosive metallic compounds.
Extinguishing
Media: Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Reduce airborne dust and prevent
scattering by moistening with water. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
|
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Use with
adequate ventilation. Minimize dust generation and accumulation. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage: Do not store in direct sunlight.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area
away from incompatible substances.
|
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Copper(I) iodide |
none listed |
none listed |
none
listed |
OSHA Vacated PELs:
Copper(I) iodide: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear appropriate
protective clothing to prevent skin exposure.
Respirators: Follow the
OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
|
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white to gray-beige
Odor: Not available.
pH: Not available.
Vapor Pressure: 10 mm Hg
Vapor
Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1290 deg C
Freezing/Melting Point:605 deg C
Autoignition Temperature:
Not applicable.
Flash Point: Not applicable.
Decomposition
Temperature:Not available.
NFPA Rating: (estimated) Health: 1;
Flammability: 0; Reactivity: 1
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Insoluble in water.
Specific Gravity/Density:5.6200
Molecular Formula:CuI
Molecular Weight:190.4505
|
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable under normal temperatures and pressures.
Conditions
to Avoid: High temperatures, incompatible materials, light, dust generation.
Incompatibilities with Other Materials: Oxidizing agents, alkali
metals, potassium, acetylene.
Hazardous Decomposition Products:
Hydrogen iodide, iodine.
Hazardous Polymerization: Will not occur.
|
Section 11 -
Toxicological Information |
RTECS#:
CAS# 7681-65-4 unlisted.
LD50/LC50:
Not
available.
Carcinogenicity:
CAS# 7681-65-4: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects:
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
available.
|
Section 12 -
Ecological Information |
No information available.
|
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 -
Transport Information |
|
US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
|
|
|
ACRYLAMIDES |
| Hazard Class: |
|
|
|
|
6.1 |
| UN Number: |
|
|
|
|
UN2074 |
| Packing Group: |
|
|
|
|
III |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7681-65-4 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
This material contains Copper(I) iodide (listed as **
undefined **), 98 0%, (CAS# 7681-65-4) which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean
Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors. This material does
not contain any Class 2 Ozone depletors.
Clean Water Act:
None of
the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under
the CWA. None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are
considered highly hazardous by OSHA.
STATE
CAS# 7681-65-4 is not
present on state lists from CA, PA, MN, MA, FL, or NJ.
California No
Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in
Accordance with EC Directives
Hazard Symbols:
XI
Risk
Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7681-65-4: 2
Canada
CAS# 7681-65-4 is listed on Canada's DSL List. CAS#
7681-65-4 is listed on Canada's DSL List.
This product has a WHMIS
classification of D2B.
CAS# 7681-65-4 is not listed on Canada's Ingredient
Disclosure List.
Exposure Limits
CAS# 7681-65-4 (listed as **
undefined **): OEL-ARAB Republic of Egypt
:TWA 0.1 mg/m3 (fume)
OEL-AUSTRALIA:TWA 0.2 mg/m3 (fume) OEL-AUSTRAL
IA:TWA 1 mg/m3 (dust)
OEL-BELGIUM:TWA 0.2 mg/m3 (fume) OEL-BELGIUM:T
WA 1 mg/m3 (dust)
OEL-DENMARK:TWA 0.1 mg/m3 (fume) OEL-DENMARK:TWA 1
mg/m3 (dust)
OEL-FINLAND:TWA 0.2 mg/m3 (fume) OEL-FINLAND:TWA 1 mg/
m3 OEL-FINLAND:TWA 1
mg/m3 (dust) OEL-FRANCE:TWA 0.2 mg/m3 (fume) O
EL-FRANCE:TWA 1 mg/m3;STEL 2
mg/m3 (dust) OEL-GERMANY:TWA 0.1 mg/m3 (
fume) OEL-GERMANY:TWA 1 mg/m3
OEL-GERMANY:TWA 1 mg/m3 (dust) OEL-HU
NGARY:TWA 0.2 mg/m3;STEL 0.4 mg/m3
(dust) OEL-INDIA:TWA 0.2 mg/m3 (fu
me) OEL-THE NETHERLANDS:TWA 02 mg/m3
(fume) OEL-THE NETHERLANDS:TWA
1 mg/m3 (dust) OEL-THE PHILIPPINES:TWA 1.0
mg/m3 (fume) OEL-POLAND:T
WA 0.1 mg/m3 (fume) OEL-RUSSIA:STEL 0.5 ppm (1
mg/m3) (dust) OEL-SWE
DEN:TWA 0.2 mg/m3 (resp. dust) OEL-SWEDEN:TWA 0.2 mg/m3
(fume) OEL-S
WEDEN:TWA 1 mg/m3 (total dust) OEL-SWITZERLAND:TWA 0.1
mg/m3;STEL 0.2
mg/m3 (fume) OEL-SWITZERLAND:TWA 1 mg/m3;STEL 1 mg/m3
OEL-THAILAND:
TWA 0.1 mg/m3 (fume) OEL-THAILAND:TWA 1 mg/m3 OEL-UNITED
KINGDOM:TWA
0.2 mg/m3 (fume) OEL-UNITED KINGDOM:TWA 1 mg/m3 OEL IN BULGARIA,
CO
LOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEAL
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Section 16 -
Additional Information |
MSDS Creation Date:
7/07/1998
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.