Material Safety Data
Sheet
Aluminum Sulfate Octadecahydrate
ACC# 00981
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Section 1 - Chemical Product and Company
Identification |
MSDS Name: Aluminum Sulfate
Octadecahydrate
Catalog Numbers: A613 500, A613-500,
A613500
Synonyms: Aluminum trisulfate, sulfuric acid aluminum salt
Company Identification:
Fisher Scientific
1
Reagent Lane
Fair Lawn, NJ
07410
For information, call: 201-796-7100
Emergency
Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7784-31-8 |
Aluminum Sulfate Octadecahydrate |
100 |
unlisted
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Hazard Symbols: None listed.
Risk Phrases: None listed.
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Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. Caution! May cause respiratory and
digestive tract irritation. May cause mechanical eye and skin irritation. This
is expected to be a low hazard for usual industrial handling.
Target
Organs: None.
Potential Health
Effects
Eye: Dust may cause mechanical
irritation.
Skin: May cause skin irritation. Low hazard for
usual industrial handling.
Ingestion: Ingestion of large
amounts may cause gastrointestinal irritation. Expected to be a low ingestion
hazard.
Inhalation: May cause respiratory tract irritation.
Low hazard for usual industrial handling.
Chronic: No
information found.
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Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of soap and water for at least
15 minutes while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion: If victim is
conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately.
If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical aid if cough or other symptoms appear.
Notes to
Physician: Treat symptomatically and supportively.
Antidote: None reported.
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Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear.
Extinguishing Media: For small fires, use water
spray, dry chemical, carbon dioxide or chemical foam.
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Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Avoid generating dusty conditions.
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Section 7 - Handling
and Storage |
Handling: Use with adequate ventilation. Minimize
dust generation and accumulation. Avoid contact with skin and eyes. Avoid
ingestion and inhalation.
Storage: Store in a tightly
closed container. Keep from contact with oxidizing materials. Store in a cool,
dry, well-ventilated area away from incompatible substances. Keep away from
water.
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Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Aluminum Sulfate Octadecahydrate |
none listed |
none listed |
none
listed |
OSHA Vacated PELs: Aluminum
Sulfate Octadecahydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate gloves to prevent
skin exposure.
Clothing: Wear appropriate protective
clothing to minimize contact with skin.
Respirators: Follow the OSHA
respirator regulations found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
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Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: none reported
pH:
Acidic in solution.
Vapor Pressure: Negligible.
Vapor
Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:189 deg F
Autoignition Temperature:
Not applicable.
Flash Point: Not applicable.
Decomposition
Temperature:189 deg F
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not
available.
Solubility: 86.9% at 32 F
Specific
Gravity/Density:1.69 at 62øF
Molecular Formula:Al2(SO4)3.18H2O
Molecular Weight:666.377
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Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable.
Conditions to Avoid: Incompatible materials,
moisture.
Incompatibilities with Other Materials: Incompatible with
strong oxidizing agents. Decomposes in water which may generate quantities of
heat or pressure.
Hazardous Decomposition Products: Oxides of sulfur,
aluminum oxide.
Hazardous Polymerization: Has not been reported.
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Section 11 -
Toxicological Information |
RTECS#:
CAS# 7784-31-8: WS5697000
LD50/LC50:
CAS#
7784-31-8:
Oral, mouse: LD50 = >9 gm/kg;
Oral, rat: LD50 = >9
gm/kg;
Carcinogenicity:
CAS# 7784-31-8: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects:
No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data
available.
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Section 12 -
Ecological Information |
No information available.
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Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
| Shipping Name: |
No information available. |
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No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 7784-31-8 is not listed on the
TSCA inventory. It is for research and development use only.
Health &
Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals
in this product are under a Chemical Test Rule.
Section 12b
None
of the chemicals are listed under TSCA Section 12b.
TSCA Significant New
Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this
material have an RQ.
Section 302 (TPQ)
None of the chemicals in
this product have a TPQ.
SARA Codes
CAS # 7784-31-8: acute,
chronic.
Section 313
This material contains Aluminum Sulfate
Octadecahydrate (listed as ** undefined **), 100%, (CAS# 7784-31-8) which is
subject to the reporting requirements of Section 313 of SARA Title III and 40
CFR Part 373.
Clean Air Act:
This material does not contain any
hazardous air pollutants. This material does not contain any Class 1 Ozone
depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed
as Hazardous Substances under the CWA. None of the chemicals in this product are
listed as Priority Pollutants under the CWA. None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None
of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7784-31-8 is not present on state lists from CA, PA,
MN, MA, FL, or NJ.
California No Significant Risk Level: None of the
chemicals in this product are listed. European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
Not available.
Risk
Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 7784-31-8: No information available.
Canada
Canada
None of the chemicals in this product
are listed on the DSL or NDSL list. WHMIS: Not available.
CAS# 7784-31-8 is
not listed on Canada's Ingredient Disclosure List.
Exposure
Limits
CAS# 7784-31-8 (listed as ** undefined **): OEL-AUSTRALIA:TWA 10
mg/m3
OEL-AUSTRALIA:TWA 2 mg/m3 (salts) OEL-AUSTRALIA:TWA 5 mg/m3 (fumes)
OEL-AUSTRALIA:TWA 5 mg/m3 (resp. dust) OEL-BELGIUM:TWA 10 mg/m3 OE
L-BELGIUM:TWA 2 mg/m3 (salts) OEL-BELGIUM:TWA 5 mg/m3 (fumes)
OEL-BE
LGIUM:TWA 5 mg/m3 (resp. dust) OEL-DENMARK:TWA 10 mg/m3 (resp. dust)
OEL-DENMARK:TWA 2 mg/m3 (salts) OEL-DENMARK:TWA 5 mg/m3 (fumes) OEL
-FINLAND:TWA 2 mg/m3 (salts) OEL-FRANCE:TWA 10 mg/m3 OEL-FRANCE:TWA
2
mg/m3 (salts) OEL-FRANCE:TWA 5 mg/m3 (fumes) OEL-FRANCE:TWA 5 mg/m
3 (resp.
dust) OEL-GERMANY:TWA 6 mg/m3 OEL-HUNGARY:STEL 5 mg/m3 OEL
-HUNGARY:TWA 2
mg/m3;STEL 4 mg/m3 (salts) JAN9 OEL-THE NETHERLANDS:TW
A 10 mg/m3 (resp.
dust) OEL-THE NETHERLANDS:TWA 2 mg/m3 (salts) OEL-
RUSSIA:STEL 2 mg/m3
OEL-SWEDEN:TWA 10 mg/m3 (resp. dust) OEL-SWEDEN:
TWA 2 mg/m3 (salts)
OEL-SWEDEN:TWA 4 mg/m3 OEL-SWEDEN:TWA 5 mg/m3 (r
esp. dust)
OEL-SWITZERLAND:TWA 2 mg/m3 (salts) OEL-SWITZERLAND:TWA 6
mg/m3 (fumes)
OEL-SWITZERLAND:TWA 6 mg/m3 OEL-SWITZERLAND:TWA 6 mg/
m3 (resp. dust)
OEL-UNITED KINGDOM:TWA 10 mg/m3;STEL 20 mg/m3 OEL-UN
ITED KINGDOM:TWA 10
mg/m3;STEL 20 mg/m3 (resp. dust) OEL-UNITED KINGD
OM:TWA 2 mg/m3 (salts) OEL
IN BULGARIA, COLOMBIA, JOR
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Section 16 -
Additional Information |
MSDS Creation Date:
9/02/1997
Revision #1 Date: 8/02/2000
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.